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  • Space Communications, Spacecraft Communications, Command and Tracking  (1)
  • conformation  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inorganic and organometallic polymers and materials 1 (1991), S. 3-35 
    ISSN: 1572-8870
    Keywords: Fluorescence ; polysilane ; σ conjugation ; conformation ; segment distribution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A comprehensive study of the electronic absorption and emission spectra and the fluorescence quantum yield and lifetime of seven poly(di-n-alkylsilane)s and of three isotopically labelled poly(di-n-hexylsilane)s in hydrocarbon solution at room temperature is reported. Also reported are fluorescence polarization and carbon tetrachloride quenching of fluorescence of poly(di-n-hexylsilane). The observed fluorescence spectra, quantum yield, and polarization depend on the selected excitation energy in a very characteristic fashion, whereas the fluorescence lifetime does not; however, it depends on the selected emission energy. These characteristic dependencies are qualitatively accounted for by the previously proposed segment distribution model if one assumes that the photophysical behavior at higher excitation energies is strongly affected by the presence of a low-lying weakly allowed state in short-segment chromophores and the behavior at lower excitation energies is dictated by the selective excitation of emitting long-segment chromophores.
    Type of Medium: Electronic Resource
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  • 2
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    In:  CASI
    Publication Date: 2019-07-13
    Description: NASA has been interested in wireless communications for many years, especially when the crew size of the International Space Station (ISS) was reduced to two members. NASA began a study to find ways to improve crew efficiency to make sure the ISS could be maintained with limited crew capacity and still be a valuable research testbed in Low-Earth Orbit (LEO). Currently the ISS audio system requires astronauts to be tethered to the audio system, specifically a device called the Audio Terminal Unit (ATU). Wireless communications would remove the tether and allow astronauts to freely float from experiment to experiment without having to worry about moving and reconnecting the associated cabling or finding the space equivalent of an extension cord. A wireless communication system would also improve safety and reduce system susceptibility to Electromagnetic Interference (EMI). Safety would be improved because a crewmember could quickly escape a fire while maintaining communications with the ground and other crewmembers at any location. In addition, it would allow the crew to overcome the volume limitations of the ISS ATU. This is especially important to the Portable Breathing Apparatus (PBA). The next generation of space vehicles and habitats also demand wireless attention. Orion will carry up to six crewmembers in a relatively small cabin. Yet, wireless could become a driving factor to reduce launch weight and increase habitable volume. Six crewmembers, each tethered to a panel, could result in a wiring mess even in nominal operations. In addition to Orion, research is being conducted to determine if Bluetooth is appropriate for Lunar Habitat applications.
    Keywords: Space Communications, Spacecraft Communications, Command and Tracking
    Type: Symposium for Space Applications of Wireless and RFID; May 08, 2007 - May 09, 2007; Houston, TX; United States
    Format: application/pdf
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