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  • Silius mine;  (1)
  • sediment  (1)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Environmental monitoring and assessment 58 (1999), S. 23-37 
    ISSN: 1573-2959
    Schlagwort(e): heavy metal ; sea water ; sediment ; spectroscopy ; voltammetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract In this present work the distribution of heavy metals in sea water and sediments of the Salerno Gulf is measured. The elements determined were Cu, Pb, Cd, Zn and Hg, employing, as instrumental techniques, either differential pulse anodic stripping voltammetry (DPASV) or graphite furnace atomic absorption spectroscopy (GFAAS). A comparison of the results of the two analytical techniques is also made. Mercury determination was carried out employing the cold vapour atomic absorption spectroscopy (CVAAS) technique, with SnCl2 as the reducing agent. The sample digestion was performed by a new procedure using concentrated suprapure H2SO4–K2Cr2O7 mixture. The accuracy and precision of the analytical procedure were evaluated employing Sea Water BCR-CRM 403 and Estuarine Sediment BCR-CRM 277 as reference materials. Accuracy, expressed as relative error e and precision, expressed as relative standard deviation sr, were in order of 2 to 5%. For both matrices, the detection limits, for all the elements, were in the range μg g-1 to ng g-1.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2022-02-02
    Beschreibung: The present research represents an approach toward the recycling of extractive waste inspired by circular economy and sustainability that is developed in accordance with Goal 12 of the United Nations 2030 Agenda for Sustainable Development Goals. A new procedure for the recovery of REEs from fluorite–barite–galena ores with calcite gangue from the Silius mine (Sardinia, Italy) is presented. The considered samples are waste materials of Silius mineralization, collected in the old processing plant of Assemini (near Cagliari). In this orebody, REE minerals consist of prevailing synchysite (a REE-bearing fluorocarbonate) and subordinate xenotime-Y (a Y-bearing phosphate). REE fluorocarbonates are extracted using 50% K2CO3 as the leaching solution, at 100 °C. Using a solution (mL)/sample (g) ratio of 25, about 10% of the total REE content of the considered sample is extracted within 1 h. At the laboratory scale, such alkaline leaching of REE from the waste materials allows the recovery of the CO2 produced as K2CO3 from concentrated KOH, in accordance with a circular flow. Further work is ongoing to scale up the process into a pilot plant, to prove that the method developed within this research can be economically feasible, socially suitable, and environmentally respectful.
    Beschreibung: Published
    Beschreibung: 14000
    Beschreibung: 1TR. Georisorse
    Beschreibung: JCR Journal
    Schlagwort(e): REE extraction; ; waste materials recycling ; alkaline leaching; ; Silius mine; ; Sardinia (Italy); ; circular economy
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Erwartet Verfügbarkeit
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