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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 26 (1980), S. 816-827 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The purpose of this paper is to analyze how the settling velocity of a dispersion of spherical particles (that is, drops of arbitrary viscosity) depends on concentration. The procedure used entirely avoids the divergent integrals which previous workers in this field have been forced to deal with and yields explicit formulas for the sedimentation velocity. These formulas, accurate to first order in the particle volume fraction, depend on both the physical characteristics of the particles (size, buoyant density, viscosity ratio) as well as on any long range forces (for example, electrical double layer repulsions or van der Waals attraction) which may exist between particles. Sample calculations are given for globular proteins subject to double layer repulsions and for micron size colloids which experience van der Waals attractions in addition to the electrostatics. In the latter case, it is shown how the Hamaker constant can be extracted from sedimentation data. The analysis is extended to more concentrated suspensions by assuming that the hydrodynamic interactions among particles are pairwise additive; comparison with published data shows this analysis to be reasonably accurate, even for dense suspensions, without any adjustable parameters.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 9 (1971), S. 413-417 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2016-05-05
    Description: The Afar Depression and its adjacent areas are underlain by an upper mantle marked by some of the world's largest negative velocity anomalies, which are frequently attributed to the thermal influences of a lower-mantle plume. In spite of numerous studies, however, the existence of a plume beneath the area remains enigmatic, partially due to inadequate quantities of broad-band seismic data and the limited vertical resolution at the mantle transition zone (MTZ) depth of the techniques employed by previous investigations. In this study, we use an unprecedented quantity (over 14 500) of P -to- S receiver functions (RFs) recorded by 139 stations from 12 networks to image the 410 and 660 km discontinuities and map the spatial variation of the thickness of the MTZ. Non-linear stacking of the RFs under a 1-D velocity model shows robust P -to- S conversions from both discontinuities, and their apparent depths indicate the presence of an upper-mantle low-velocity zone beneath the entire study area. The Afar Depression and the northern Main Ethiopian Rift are characterized by an apparent 40–60 km depression of both MTZ discontinuities and a normal MTZ thickness. The simplest and most probable interpretation of these observations is that the apparent depressions are solely caused by velocity perturbations in the upper mantle and not by deeper processes causing temperature or hydration anomalies within the MTZ. Thickening of the MTZ on the order of 15 km beneath the southern Arabian Plate, southern Red Sea and western Gulf of Aden, which comprise the southward extension of the Afro-Arabian Dome, could reflect long-term hydration of the MTZ. A 20 km thinning of the MTZ beneath the western Ethiopian Plateau is observed and interpreted as evidence for a possible mantle plume stem originating from the lower mantle.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 4
    Publication Date: 2015-07-04
    Description: Mechanisms leading to the initiation and early-stage development of continental rifts remain enigmatic, in spite of numerous studies. Among the various rifting models, which were developed mostly based on studies of mature rifts, far-field stresses originating from plate interactions (passive rifting) and nearby active mantle upwelling (active rifting) are commonly used to explain rift dynamics. Situated atop of the hypothesized African Superplume, the incipient Okavango Rift Zone (ORZ) of northern Botswana is ideal to investigate the role of mantle plumes in rift initiation and development, as well as the interaction between the upper and lower mantle. The ORZ developed within the Neoproterozoic Damara belt between the Congo Craton to the northwest and the Kalahari Craton to the southeast. Mantle structure and thermal status beneath the ORZ are poorly known, mostly due to a complete paucity of broad-band seismic stations in the area. As a component of an interdisciplinary project funded by the United States National Science Foundation, a broad-band seismic array was deployed over a 2-yr period between mid-2012 and mid-2014 along a profile 756 km in length. Using P -to- S receiver functions (RFs) recorded by the stations, the 410 and 660 km discontinuities bordering the mantle transition zone (MTZ) are imaged for the first time. When a standard Earth model is used for the stacking of RFs, the apparent depths of both discontinuities beneath the Kalahari Craton are about 15 km shallower than those beneath the Congo Craton. Using teleseismic P - and S -wave traveltime residuals obtained by this study and lithospheric thickness estimated by previous studies, we conclude that the apparent shallowing is the result of a 100–150 km difference in the thickness of the lithosphere between the two cratons. Relative to the adjacent tectonically stable areas, no significant anomalies in the depth of the MTZ discontinuities or in teleseismic P - and S -wave traveltime residuals are found beneath the ORZ. These observations imply an absence of significant thermal anomalies in the MTZ and in the upper mantle beneath the incipient rift, ruling out the role of mantle plumes in the initiation of the ORZ. We propose that the initiation and development of the ORZ were the consequences of relative movements between the South African block and the rest of the African plate along a zone of lithospheric weakness between the Congo and Kalahari cratons. An area of thinner-than-normal MTZ is found at the SW corner of the study area. This anomaly, if confirmed by future studies, could suggest significant transferring of heat from the lower to the upper mantle.
    Keywords: Seismology
    Print ISSN: 0956-540X
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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