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  • 1
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    Validation test of advanced technology for IPV nickel-hydrogen flight cells: Update (1992)
    In:  CASI
    Details
    Publication Date: 2019-06-28
    Description: Individual pressure vessel (IPV) nickel-hydrogen technology was advanced at NASA Lewis and under Lewis contracts with the intention of improving cycle life and performance. One advancement was to use 26 percent potassium hydroxide (KOH) electrolyte to improve cycle life. Another advancement was to modify the state-of-the-art cell design to eliminate identified failure modes. The modified design is referred to as the advanced design. A breakthrough in the low-earth-orbit (LEO) cycle life of IPV nickel-hydrogen cells has been previously reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3,500 cycles for cells containing 31 percent KOH. The boiler plate test results are in the process of being validated using flight hardware and real time LEO testing at the Naval Weapons Support Center (NWSC), Crane, Indiana under a NASA Lewis Contract. An advanced 125 Ah IPV nickel-hydrogen cell was designed. The primary function of the advanced cell is to store and deliver energy for long-term, LEO spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent KOH electrolyte; (2) use of a patented catalyzed wall wick; (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management; and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion due to charge/discharge cycling. The significant improvements resulting from these innovations are: extended cycle life; enhanced thermal, electrolyte, and oxygen management; and accommodation of nickel electrode expansion. The advanced cell design is in the process of being validated using real time LEO cycle life testing of NWSC, Crane, Indiana. An update of validation test results confirming this technology is presented.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA-TM-105689 , E-7069 , NAS 1.15:105689 , Intersociety Energy Conversion Engineering Conference
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    NASA TECHNICAL REPORTS
  • 2
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    Effect of LEO cycling on 125 Ah advanced design IPV nickel-hydrogen flight cells - An update (1991)
    In:  Other Sources
    Details
    Publication Date: 2019-08-28
    Description: An update of validation test results confirming the breakthrough in LEO cycle life of nickel-hydrogen cells containing 26 percent potassium hydroxide (KOH) electrolyte is presented. A breakthrough in the LEO cycle life of individual pressure vessel nickel-hydrogen cells is reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3500 cycles for cells containing 31 percent KOH.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: IECEC ''91: Intersociety Energy Conversion Engineering Conference; Aug 04, 1991 - Aug 09, 1991; Boston, MA; United States
    Format: text
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    NASA TECHNICAL REPORTS
  • 3
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    Validation test of 125 Ah advanced design IPV nickel-hydrogen flight cells (1993)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: An update of validation test results confirming the advanced design nickel-hydrogen cell is presented. An advanced 125 Ah individual pressure vessel (IPV) nickel-hydrogen cell was designed. The primary function of the advanced cell is to store and deliver energy for long-term, Low-Earth-Orbit (LEO) spacecraft missions. The new features of this design, which are not incorporated in state-of-the-art design cells, are: (1) use of 26 percent rather than 31 percent potassium hydroxide (KOH) electrolyte; (2) use of a patented catalyzed wall wick; (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management; and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion due to charge/discharge cycling. The significant improvements resulting from these innovations are extended cycle life; enhanced thermal, electrolyte, and oxygen management; and accommodation of nickel electrode expansion. Six 125 Ah flight cells based on this design were fabricated by Eagle-Picher. Three of the cells contain all of the advanced features (test cells) and three are the same as the test cells except they do not have catalyst on the wall wick (control cells). All six cells are in the process of being evaluated in a LEO cycle life test at the Naval Weapons Support Center, Crane, IN, under a NASA Lewis Research Center contract. The catalyzed wall wick cells have been cycled for over 19000 cycles with no cell failures in the continuing test. Two of the noncatalyzed wall wick cells failed (cycles 9588 and 13,900).
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA-TM-105912 , E-7393 , NAS 1.15:105912 , Annual Battery Conference on Applications and Advances; Jan 12, 1993 - Jan 14, 1993; Long Beach, CA; United States
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 4
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    Effect of LEO cycling on 125 Ah advanced design IPV nickel-hydrogen battery cells (1990)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: An advanced 125 Ah individual pressure vessel (IPV) nickel-hydrogen cell was designed. The primary function of the advanced cell is to store and deliver energy for long-term, low earth-orbit (LEO) spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent potassium hydroxide (KOH) electrolyte, (2) use of a patented catalyzed wall wick, (3) use of serrated-edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management, and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion. Six 125-Ah flight cells based on this design were fabricated by Eagle-Picher. Three of the cells contain all of the advanced features (test cells) and three are the same as the test cells except they don't have catalyst on the wall wick (control cells). All six cells are in the process of being evaluated in a LEO cycle life test. The cells have accumulated about 4700 LEO cycles (60 percent DOD 10 C). There have been no cell failures; the catalyzed wall wick cells, however, are performing better.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: Intersociety Energy Conversion Engineering Conference; Aug 12, 1990 - Aug 17, 1990; Reno, NV; United States
    Format: text
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    NASA TECHNICAL REPORTS
  • 5
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    Effect of KOH concentration on LEO cycle life of IPV nickel-hydrogen flight cells - An update (1991)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: An update of validation test results confirming the breakthrough in LEO cycle life of nickel-hydrogen cells containing 26 percent potassium hydroxide (KOH) electrolyte is presented. A breakthrough in the LEO cycle life of individual pressure vessel nickel-hydrogen cells is reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3500 cycles for cells containing 31 percent KOH.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: IECEC ''91: Intersociety Energy Conversion Engineering Conference; Aug 04, 1991 - Aug 09, 1991; Boston, MA; United States
    Format: text
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    NASA TECHNICAL REPORTS
  • 6
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    Effect of KOH concentration on LEO cycle life of IPV nickel-hydrogen flight battery cells (1990)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: A breakthrough in the low-earth-orbit (LEO) cycle life of individual pressure vessel (IPV) nickel hydrogen battery cells is reported. The cycle life of boiler plate cells containing 26 percent potassium hydroxide (KOH) electrolyte was about 40,000 LEO cycles compared to 3500 cycles for cells containing 31 percent KOH. The effect of KOH concentration on cycle life was studied. The cycle regime was a stressful accelerated LEO, which consisted of a 27.5 min charge followed by a 17.5 min charge (2 x normal rate). The depth of discharge (DOD) was 80 percent. The cell temperature was maintained at 23 C. The next step is to validate these results using flight hardware and real time LEO test. NASA Lewis has a contract with the Naval Weapons Support Center (NWSC), Crane, Indiana to validate the boiler plate test results. Six 48 A-hr Hughes recirculation design IPV nickel-hydrogen flight battery cells are being evaluated. Three of the cells contain 26 percent KOH (test cells) and three contain 31 percent KOH (control cells). They are undergoing real time LEO cycle life testing. The cycle regime is a 90-min LEO orbit consisting of a 54-min charge followed by a 36-min discharge. The depth-of-discharge is 80 percent. The cell temperature is maintained at 10 C. The cells were cycled for over 8000 cycles in the continuing test. There were no failures for the cells containing 26 percent KOH. There were two failures, however, for the cells containing 31 percent KOH.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: Intersociety Energy Conversion Engineering Conference; Aug 12, 1990 - Aug 17, 1990; Reno, NV; United States
    Format: text
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    NASA TECHNICAL REPORTS
  • 7
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    Destructive physical analysis results of Ni/H2 cells cycled in LEO regime (1991)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: Six 48-Ah individual pressure vessel (IPV) Ni/H2 cells containing 26 and 31 percent KOH electrolyte were life cycle tested in low Earth orbit. All three cells containing 31 percent KOH failed (3729, 4165, and 11,355 cycles), while those with 26 percent KOH were cycled over 14,000 times in the continuing test. Destructive physical analysis (DPA) of the failed cells included visual inspections, measurements of electrode thickness, scanning electron microscopy, chemical analysis, and measurements of nickel electrode capacity in an electrolyte flooded cell. The cycling failure was due to a decrease of nickel electrode capacity. As possible causes of the capacity decrease, researchers observed electrode expansion, rupture, and corrosion of the nickel electrode substrate, active material redistribution, and accumulation of electrochemically undischargeable active material with cycling.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA-TM-104382 , E-6191 , NAS 1.15:104382 , Intersociety Energy Conversion Engineering Conference; Aug 04, 1991 - Aug 09, 1991; Boston, MA; United States
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 8
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    Effect of KOH concentration on LEO cycle life of IPV nickel-hydrogen flight cells. An update (1991)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: An update of validation test results confirming the breakthrough in LEO cycle life of nickel-hydrogen cells containing 26 percent potassium hydroxide (KOH) electrolyte is presented. A breakthrough in the LEO cycle life of individual pressure vessel nickel-hydrogen cells is reported. The cycle life of boiler plate cells containing 26 percent KOH electrolyte was about 40,000 LEO cycles compared to 3500 cycles for cells containing 31 percent KOH.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA-TM-104383 , E-6192 , NAS 1.15:104383 , Intersociety Energy Conversion Engineering Conference; Aug 04, 1991 - Aug 09, 1991; Boston, MA; United States
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 9
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    Effect of LEO cycling on 125 Ah advanced design IPV nickel-hydrogen flight cells. An update (1991)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: Validation testing of the NASA Lewis 125 Ah advanced design individual pressure vessel (IPV) nickel-hydrogen flight cells was conducted. Work consisted of characterization, storage, and cycle life testing. There was no capacity degradation after 52 days of storage with the cells in the discharged state, an open circuit, 0 C, and a hydrogen pressure of 14.5 psia. The catalyzed wall wick cells were cycled for over 11,000 cycles with no cell failures in the continuing test. One of the noncatalyzed wall wick cells failed.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA-TM-104384 , E-6193 , NAS 1.15:104384 , Intersociety Energy Conversion Engineering Conference; Aug 04, 1991 - Aug 09, 1991; Boston, MA; United States
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 10
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    Effect of LEO cycling on 125 Ah advanced design IPV nickel-hydrogen battery cells (1990)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: An advanced 125 Ah individual pressure vessel (IPV) nickel-hydrogen cell was designed. The primary function of the advanced cell, is to store and deliver energy for long term, low earth-orbit (LEO) spacecraft missions. The new features of this design are: (1) use of 26 percent rather than 31 percent potassium hydroxide (KOH) electrolyte, (2) use of a patented catalyzed wall wick, (3) use of serrated edge separators to facilitate gaseous oxygen and hydrogen flow within the cell, while still maintaining physical contact with the wall wick for electrolyte management, and (4) use of a floating rather than a fixed stack (state-of-the-art) to accommodate nickel electrode expansion. Six 125 Ah flight cells based on this design were fabricated by Eagle-Picher. Three of the cells contain all of the advanced features (test cells) and three are the same as the test cells except they don't have catalyst on the wall wick (control cells). All six cells are in the process of being evaluated in a LEO cycle life test. The cells have accumulated about 4700 LEO cycles (60 percent DOD 10 C). There have been no cell failures, the catalyzed wall wick cells however, are performing better.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA-TM-103128 , E-5458 , NAS 1.15:103128 , Intersociety Energy Conversion Engineering Conference; Aug 12, 1990 - Aug 17, 1990; Reno, NV; United States
    Format: application/pdf
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    NASA TECHNICAL REPORTS
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