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  • 1
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2011-08-19
    Description: The upward directional solidification of a binary alloy in which the rejected solute is more dense than the solvent is considered. The system is stably stratified both thermally and solutally. If heat is lost through the sidewalls, horizontal thermal gradients drive a steady double-diffusive convection. Solidification cells with small aspect ratios (width/length) A are considered, and asymptotic solutions to the steady double-diffusive system are obtained as A tends to 0 under the assumption heat losses are also small. When the thermal Grashof number is large, buoyancy boundary layers are at the sidewalls. The shape of the crystal-melt interface is determined by the coupled effects of local thermodynamic equilibrium, diffusion and convection.
    Keywords: SOLID-STATE PHYSICS
    Type: PCH/PhysicoChemical Hydrodynamics (ISSN 0191-9059); 9; 1-2,; 9-14
    Format: text
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  • 2
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2011-08-19
    Description: The existing theory on two-dimensional transitions (appropriate to thin parallel-plate geometries) is presented in such a way that it is possible to identify easily conditions for the onset of shallow cells. Conditions are given under which succinonitrile-acetone mixtures should undergo supercritical bifurcation in experimentally accessible ranges. These results suggest a means for the quantitative test of the Mullins and Sekerka (1964) model and its weakly nonlinear extensions.
    Keywords: SOLID-STATE PHYSICS
    Type: Physical Review Letters (ISSN 0031-9007); 63; 573-575
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  • 3
    facet.materialart.
    Unknown
    In:  Other Sources
    Publication Date: 2011-08-19
    Description: The upward directional solidification of a dilute binary alloy in a tall, thin, two-dimensional slot is considered. Heat losses from the sidewalls produce curved isotherms, interface deformations, and melt convection. An asymptotic approach is used which relates the small heat loss to the thinness of the solidification cell, and solutions are obtained for the resulting melt convection, interface deflection, and the distribution of heat and solute. The model is compared to the numerical results of Chang and Brown (1983) which exclude the effects of solute buoyancy and thermodynamic equilibrium at the interface. The radial segregation at the interface (consistent with both interface shapes and temperature fields) is computed, and it is found that the radial segregation is independent of interfacial shapes; the radial segregation cannot be calculated from only a knowledge of the interface shape.
    Keywords: SOLID-STATE PHYSICS
    Type: Journal of Crystal Growth (ISSN 0022-0248); 91; 4, Se; 538-556
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  • 4
    facet.materialart.
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    In:  Other Sources
    Publication Date: 2011-08-19
    Description: A modification of Ivantsov's (1947) similarity solutions is proposed which can describe phase-change processes which are limited by diffusion. The method has application to systems that have n-components and possess cross-diffusion and Soret and Dufour effects, along with convection driven by density discontinuities at the two-phase interface. Local thermal equilibrium is assumed at the interface. It is shown that analytic solutions are possible when the material properties are constant.
    Keywords: SOLID-STATE PHYSICS
    Type: Metallurgical Transactions A - Physical Metallurgy and Materials Science (ISSN 0360-2133); 20A; 225-235
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  • 5
    facet.materialart.
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    In:  Other Sources
    Publication Date: 2019-07-13
    Description: The mechanical and electrical properties of crystals produced by a unidirectional process depend strongly on the temperature and flow fields since these control the concentration of solute at the melt-crystal interface. The solute gradient there drives morphological instabilities that lead to cellular or dendritic interfaces. In the presentation several features of flow-solidification interactions will be discussed. These will include the effects of convection driven by density changes and buoyancy and the imposition of forced flow.
    Keywords: SOLID-STATE PHYSICS
    Type: Interdisciplinary issues in materials processing and manufacturing; Dec 13, 1987 - Dec 18, 1987; Boston, MA; United States
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