ISSN:
0887-624X
Keywords:
poly-β-hydroxyalkanoates
;
bacterial polyesters
;
Pseudomonas oleovorans
;
functional polyesters
;
reserve polyesters
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Poly-3-hydroxyalkanoates (PHAs) containing repeating units with terminal alkene substituents at the 3-position were produced by Pseudomonas oleovorans grown with either 7-octeneoic acid [OA(=)] alone, or 10-undeceneoic acid [UND(=)] alone, or mixtures of UND(=) and either nonanoic acid (NA) or octanoic acid (OA). For the latter, the biomass and PHA yields decreased as the fraction of UND(=) increased in the mixed carbon substrates. Essentially all of the repeating units in the PHA obtained from cells grown with UND(=) alone contained terminal alkene groups, including 3-hydroxy-10-undeceneoate, 3-hydroxy-8-noneneoate, and 3-hydroxy-6-hepteneoate units, but less than half of the units in the PHA from OA(=) had alkene substituents. The PHAs obtained from cells grown with various mixtures of UND(=) and either OA or NA were random copolymers, and the fraction of units with alkene substituents in these polymers increased in proportion to the fraction of UND(=) in the mixed carbon substrates. © 1995 John Wiley & Sons, Inc.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1995.080330819
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