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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 31 (1980), S. 21-27 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Corrosion by acids formed by oxidation of bitumineous roof coveringsIn recent years there has been an increased number of case histories involving metallic roof draining systems in connection with bitumineous materials. An evaluation of 64 histories has shown that 60% of the cases could be attributed to unprotected bitumineous coatings, mastix and undefined special paint coats, 24% to weld-seems without slate covering and about 16% to inadequately sanded roof areas. No damages were counted in the case of roofs with adequate gravel or slate covering. Short-time weathering in the laboratory has confirmed these findings. It could be shown that bitumineous materials are oxidized during weathering and formed carbonic acid. It has further been shown that reaction products of chemicals used for blowing or improving bitumineous materials are not the cause of such damages. The oxidation and thus the formations of acids can be used by adequate sanding of the bitumineous materials so that the damage to roof draining systems can be excluded.
    Notes: In den letzten Jahren kam es vermehrt zu Schäden an Dachentwässerungssystemen aus metallischen Werkstoffen in Verbindung mit bituminösen Baustoffen.Eine Untersuchung von 64 Schadensfällen ergab, daß 60% der Schäden auf ungeschützte bituminöse Anstriche, Spachtelmassen und nicht definierte Spezialanstriche, 24% auf ungeschützte, d. h. nicht beschieferte Schweißbahnen und etwa 16% auf Dachflächen mit lückenhafter Bestreuung entfallen. Dagegen traten bei ordungsgemäß bekiesten oder beschieferten Dachflächen keine Schäden auf. Im Labor durchgeführte Kurzzeitbewitterungsprüfungen bestätigten diese Untersuchung. Es zeigte sich, daß Bitumen unter Einwirkung von Witterungseinflüssen oxidiert und dabei Carbonsäuren entstehen. Es konnte weiterhin geklärt werden, daß Reaktionsprodukte von Chemikalien, die beim Blasen oder zur Vergütung von Bitumen eingesetzt werden, als Verursacher ausscheiden.Nur eine ordungsgemäße Bestreuung schwächt die Oxidation und damit die Säurebildung, so daß eine Gefährdung metallischer Dachentwässerungssysteme ausgeschlossen werden kann.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Polycarbonate (PC) based on 4,4'-dihydroxydiphenyl-2,2-propane has adchieved an outstanding market relevance due to its extraordinary physical and technical properties, especially due to the combination of excellent impact strength and high heat distortion temperature (HDT) combined with good optical and electrical properties.This very attractive balance of properties has led to a broad and still expanding use of PC in different optical application areas. Therefore it has reached a significant importance as a material for glasing (compact sheet and twin wall sheet) and also for optical lenses. For lenses the high refraction index of PC (n = 1,58) and its low density have shown as additional advantages. Recently PC was introduced as a base material for polymeric optical fibers (POF) in the market: Despite its inherently high optical loss (about 800 dB/km at λ = 820 nm) PC has proved as an attractive material because of its high refractive index (cheap cladding, narrow bending radii) and its good HDT (use at relatively high temperatures, e.g. near the engine of automobiles), so far the maximum fiber length will not exceed 30 m.During the last decade PC with extremely high flow and purity became the material of choice for music consumer industry (compact disk: CD) and for optical data storage technology. So far all the CDs were produced worldwide from PC (1988: 450 Mio CD, 1989 about 650 Mio CD). These special PC grades are used for WORM disks (write once read multiple) and EOD disks (erasable optical disks) with diameter up to 13 cm. These disks are still in the phase of market introduction. For disk diameters greater than 13 cm up to 30 cm experimental products with very low birefringence combined with increased stiffness are currently under development (e.g. blends of modified PC with modified SAN).The continuous improvement of the commercial PC grades and the new development of structurely modified PC and special blends based on PC will lead to a further increasing consumption of PC and to further expanding applications of PC especially in the optical market area.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 195 (1994), S. 793-802 
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Aliphatic homopolyesters and copolyesters based on 1,3-propanediol and containing terephthalic acid as aromatic compounds and sebacic acid as aliphatic compound were synthesized by condensation in bulk. Intrinsic viscosity and weight-average molecular weight were measured. Melting temperatures were studied by differential scanning calorimetry. For all polyesters the biodegradability was tested. Test media were inoculated with either municipal compost eluates or decanted sewage sludge. Criteria measured were visible changes, weight loss, and scanning electron microscopy indicating the visible changes of the surface. Compositions of copolyesters were characterized by 13C NMR spectroscopy. As a major result it is concluded that biodegradability depends substantially on the sequential structure of the polymer.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 12 (1974), S. 73-80 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 16 (1978), S. 607-614 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 66 (1994), S. 1272-1273 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 904-907 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 1199-1199 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 1383-1391 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A novel planar ↔ nonplanar visual thermochromic conformational transition of polydiacetylene molecules in poor solvents is reported. The conformational transition is associated with both a color change (blue or red ↔ yellow) and a change in the state; the yellow solution (liquid) transforms to a blue or red gel (solid). The color transition occurs within a narrow range of temperature and has a large associated hysteresis. The enthalpy of the conformational transition is 29 kJ/mole of repeat unit. Fourier-transform infrared studies show that molecules acquire a planar conformation in red or blue gels by formation of intramolecular H bonds between the adjacent substituent groups. Virtually all H bonds break (a nonplanar conformation) when the gels turn into yellow solutions.
    Additional Material: 6 Ill.
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