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  • 1
    Electronic Resource
    Electronic Resource
    Modification of nitrocellulose by graft copolymerization (1978)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 16 (1978), S. 457-459 
    Details
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1978.130160904
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  • 2
    Electronic Resource
    Electronic Resource
    Estimation of reactivity ratios of acrylate copolymers by 1H-NMR (1983)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 761-765 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Copolymers of methyl methacrylate (MMA) and dimethylaminomethacrylate (DMAEM) are useful for binding of enzymes. Copolymerization of MMA and DMAEM was carried out in dioxane using benzoyl peroxide as an initiator at 70°C. The estimation of the composition of MMA and DMAEM in copolymer was carried by 1H-NMR. The reactivity ratio was found to be r1 = 1.20 and r2 = 0.19 by Kelen-Tüdös method and r1 = 1.24 and r2 = 0.21 by Finemann-Ross method.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1983.170210311
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  • 3
    Electronic Resource
    Electronic Resource
    Free radical copolymerization of poly(n-butyl methacrylate) onto polychloroprene (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 1551-1558 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft copolymerization of n-butyl methacrylate onto polychloroprene was carried out in toluene using benzoyl peroxide as an initiator. The polychloroprene-g-poly(n-butyl methacrylate) was isolated from the copolymerization product by extracting with hexane. Infrared (IR) spectra and nuclear magnetic resonance (NMR) of graft copolymer showed the occurrence of grafting. Percentage of grafting and grafting efficiency calculated under different experimental conditions were discussed. The mechanism of grafting seems to occur by chain transfer, as evidenced by a decrease in chlorine content during the experiment.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070370609
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  • 4
    Electronic Resource
    Electronic Resource
    Glass fiber reinforced polypropylene/EPDM blends. II. Mechanical properties and morphology (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 451-462 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tensile and impact properties of the ternary system polypropylene (PP)/ethylene propylene diene elastomer (EPDM)/glass fiber (GF) and the corresponding binary systems PP/EPDM blend and PP/GF composite are studied. Results are presented and analyzed as functions of compositional variables, viz., (i) matrix PP/EPDM blending ratio at constant GF loadings and (ii) GF loading at constant matrix blending ratios for the ternary system and (iii) EPDM content for PP/EPDM binary system and (iv) GF content for the binary system PP/GF, respectively. The role of individual components EPDM and GF in these mechanical properties is discussed and their combined effects are inspected at certain composition ranges. Theoretical analysis of tensile data is presented which reveals the effect of EPDM on the reinforcing effect of GF. Unlike the conventional role of an elastomer, increase of EPDM content in the presence of GF increases the modulus of the ternary system. Impact strength of the ternary system increases with increasing GF content both in the presence and absence of EPDM, showing a distinct minimum at matrix blending ratio PP/EPDM 90/10. Scanning electron micrographs of impact-fractured surfaces are presented to illustrate the dispersion of the two phases of the polyblend matrix, fiber alignment, and the fiber interface.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1991.070430306
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  • 5
    Electronic Resource
    Electronic Resource
    Melt-rheological properties of PP/EVA blend (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 281-293 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This paper describes a study of melt-rheological properties of the binary blend of isotactic polypropylene (PP) and ethylene-vinyl acetate copolymer (EVA) at varying blending ratios (from 0 to 40 wt % EVA content) and using three samples of EVA containing different vinyl acetate contents (VA %), viz. 9, 12, and 19%. Measurements made on a capillary rheometer at three different temperatures (210, 220, and 230°C) in a shear stress range of 104-106 Pa (shear rate 101-104 s-1) are presented and discussed for the effects of blend composition and shear stress on the flow curves, melt viscosity and melt elasticity. Morphology of the blend studied through scanning electron microscopy revealed distinct differences in size and number density of dispersed EVA droplets, which are discussed in terms of the variation of average size and number density of the dispersed EVA droplets as a function of blend composition and shear stress. Melt-rheological properties and morphology of dispersion are correlated and found quite consistent.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1992.070460209
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  • 6
    Electronic Resource
    Electronic Resource
    Grafting of methyl methacrylate to nitrocellulose by ceric ions (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 2923-2928 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Studies were carried out on grafting of various vinyl monomers to nitrocellulose by ceric ions. It was observed that graft copolymerization occurred only with methyl methacrylate (MMA) and methyl acrylate monomer. The variables such as initiator concentration, monomer concentration, time of grafting, and nitrocellulose content on grafting of MMA are discussed. By hydrolyzing away the nitrocellulose backbone, the grafted poly(methyl methacrylate) branches were isolated and the 〉c=o peak at 1740 cm-1 in the infrared spectra of these isolated branches gave definite evidence of grafting. The molecular weight of isolated branches has been determined by viscometry. The probable mechanism of grafting may be at the α-carbon atom of primary alcohol or at a C2-C3 glycol group of the anhydro glucose unit or at the hemiacetal group of the end unit of nitrocellulose, as nitrocellulose is formed by the partial nitration of cotton cellulose.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070231009
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  • 7
    Electronic Resource
    Electronic Resource
    Mechanochemical process in cotton cellulose fiberCorrected proofs received October 22, 1982 (1983)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 1-10 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Mechanical processing of cotton cellulose by means of a fiber cutter resulted in the disaggregation and defiberation of fiber bundles, shortening of fiber length, and loss of degree of polymerization. It is evident that the mechanical energy supplied by shear forces is sufficient to cause homolytic scission of cellulose main chains. Mechanoradicals formed in the interim were verified by ESR studies. The crystallinity of cellulose was not influenced by mechanical treatments, but accessibility of the polymer was substantially increased due to the creation of new surfaces. The mechanically treated fiber inclined to proceeded oxidative chain reaction during aging. Regardless of their treatment conditions, cellulose fiber reached its limiting lower molecular weight after 100 days of aging.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1983.070280101
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  • 8
    Electronic Resource
    Electronic Resource
    Impact toughening of polypropylene by ethylene vinyl acetate copolymer (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 1303-1312 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this article we studied the potential of ethylene vinyl acetate copolymer (EVA) as an impact modifier for isotactic polypropylene (PP). PP/EVA blend in the range 0-40 wt % EVA content is studied by using three grades of EVA containing 9, 12, and 19 wt % VA. Izod impact strength measurements were made at temperatures ranging from liquid nitrogen temperature to 60°C to explore the impact-toughening effect as a function of blending ratio both at low and above ambient temperatures. The results are compared with various reported blends of PP with other elastomers. Morphological studies through scanning electron microscopy on etched impact-fractured surfaces are carried out and a correlation of morphology and impact properties at various blending ratios is presented. Finally, a mathematical analysis of the data is performed in terms of second-degree polynomial to express impact strength as a simultaneous function of two variables, and an equation is proposed that shows the best fit with the experimental data. Relevant contour diagrams, based on the proposed equation, for optimization of properties are also presented.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1992.070450718
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  • 9
    Electronic Resource
    Electronic Resource
    Melt rheology and morphology of PP/SEBS/PC ternary blend (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 47 (1993), S. 167-184 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Melt rheological properties of the ternary blend of isotactic polypropylene (PP), styreneethylene-butylene-styrene terpolymer (SEBS), and polycarbonate (PC), PP/SEBS/PC, are studied in a wide range of composition, such that PP is the matrix and SEBS and PC are the minor components, with the proportion of one varying from 0 to 30% at various fixed compositions of the other. The respective binary blends, PP/SEBS and PP/PC, studied as the reference systems for interpretation of results on the ternary blends yielded interesting new information about the morphology development and its correlation with melt rheological properties of these binary blends. The studies include the measurement of melt rheological properties on a capillary rheometer in the shear rate range 101-104 s-1 at a fixed temperature of 240°C. The data presented as conventional flow curves are analyzed for the effect of blend composition and shear rate on pseudoplasticity, melt viscosity, and melt elasticity, and role of each individual component is identified. Morphology of dispersed phases of these blends is studied through scanning electron microscopy of the cryogenically fractured and suitably etched surfaces. Variations of morphology with blend composition and shear rate showed interesting correlation with melt rheological properties, which are discussed in detail. An important finding of the morphological studies is that in the PP/SEBS/PC ternary blend the SEBS phase forms two types of morphologies depending on the blend composition and shear rate: (i) simple droplets and (ii) boundary layer at the surface of the PC droplets. © 1993 John Wiley & Sons, Inc.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1993.070470118
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  • 10
    Electronic Resource
    Electronic Resource
    Dilute solution properties and molecular characterization of poly(butyl methacrylate-co-styrene) (1973)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 11 (1973), S. 331-343 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Dilute solution properties of fractionated poly(butyl methacrylate-co-styrene) PBMAS prepared by bulk polymerization, have been investigated by means of light scattering, viscometry, and osmometry. As the composition heterogeneity was narrow, the characterization of the copolymer was effected in a single solvent by light scattering. Infrared and nuclear magnetic resonance spectra were used to determine the composition and sequence distribution of monomer units of the copolymer. The molecular weight dependence of the limiting viscosity number and of the root-mean-square end-to-end distance have been established. The Mark-Houwink relation showed that methylethyl ketone is a good solvent compared with cyclohexane. The validity of various extrapolation procedures that have been proposed to calculate the unperturbed dimensions have been examined. Root-mean-square end-to-end distances have been calculated from the Debye-Bueche and Kirkwood-Riseman methods and compared with the experimental values. The molecular weight dependence of the second virial coefficient agreed well with that calculated from the Orofino-Flory equation. The value of the steric hindrance parameter σ for the copolymer has been found to be 2.27 compared to 2.05 for poly(butyl methacrylate) and 2.22 for polystyrene, which indicates that PBMAS is a stiffer chain in solution than those of the constituent homopolymers.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1973.180110213
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