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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 3403-3421 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The various types of drag-reducing systems and their hydrodynamic shear degradation are briefly reviewed and some new measurements reported. The new measurements include the determination of the efficiency of drag reduction by a variety of systems ranging from fully flexible polymers, more rigid polymers, and asbestos fibers. These results, together with those of previous workers using fractionated polymers, show a good correlation between critical concentration and particle length. The results suggest that at the highest wall shear stress, the parameter governing the efficiency is the contour length of the particle, irrespective of its structure, stiffness, or diameter. At lower wall shear stresses, the shorter flexible molecules are less efficient, but the short rigid ones and the long flexible ones maintain their efficiency. The shear degradation of the systems was measured by repeated passages of the solution through the measuring apparatus at both high and low wall shear stresses. Drag reduction measured at low wall shear stresses is an extremely sensitive indicator of shear degradation of flexible polymers.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 155-165 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The structure of polyethylenimine in aqueous and ethanolic solutions was investigated by measuring the fluorescence polarization of dansyl conjugates. In aqueous solutions, all polyethylenimines, whatever their molecular weight, are associated into large aggregates containing rotating units having rotary relaxation times corresponding to spherical particles of molecular weight about 3-6 × 103. The interaction of polyethylenimine with very dilute solutions of linear high polymers has been investigated by fluorescence polarization measurements and by the measurement of turbulent drag. Addition of polyethylenimine causes the solutions of anionic polymers to lose their capability of reducing turbulent drag. The results are discussed in relation to the proposed structure of the anionic-cationic complexes formed in the mixtures.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 5 (1967), S. 803-806 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 4 (1966), S. 977-979 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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