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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 36 (1985), S. 265-272 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Embrittlement conditions of ferritic chromium steels and influence on the corrosion fatigue behaviourThe corrosion fatigue behavior of two ferritic stainless steels, with 18% and 28% chromium respectively, embrittled by α'- or sigma-phase has been studied in this investigation. No effect of the α'-phase on the corrosion fatigue behaviour in a 0.5 N or 4 N air saturated soldium chloride solution at 80 °C has been found. In the 4 N solution corrosion fatigue cracking of the 18% chromium steel in the solutionized as well as in the α'-embrittled condition is initiated by pitting at nonmetallic inclusions. Sigma-phase not only decreases the mechanical properties of the 28% chromium steel by heavy embrittlement but also leads to crack initiation by pitting in the 4 N solution at the interface sigma/ferrite. The pronounced decrease of the corrosion fatigue properties of the 28% chromium steel could well be correlated with chromium depletion of the ferrite matrix by precipitation of sigma phase.
    Notes: Der Einfluß der versprödenden Phasen α' und σ auf das Schwingungsrißkorrosionsverhalten der beiden rein ferritischen Chromstähle 1.4522 und 1.4575 (18% bzw. 28% Chrom) wurde untersucht. Sowohl in der 0,5 N als auch in der 4 N Natriumchloridlösung konnte keine Beeinflußung der Korrosionseigenschaften durch α'-Ausscheidung festgestellt werden. In Luft und der 0,5 N Lösung bewirkt die Ausscheidung von α'-Phase bei beiden Stählen eine Erhöhung der Schwingfestigkeit. Der Abfall der Korrosionsschwingfestigkeit in der 4 N Natriumchloridlösung wird beim 18%-Chromstahl, im lösungsgeglühten und α'-versprödeten Zustand, durch Lochfraß an nichtmetallischen Einschlüssen herbeigeführt. Die durch die α'-Ausscheidung hervorgerufene, stärker lokalisierte Oberflächenverformung führt beim 28%-Chromstahl in der 4 N Lösung ebenfalls zur Erniedrigung der Korrosionsschwingfestigkeit. Die sigma-Phase verschlechtert einerseits die mechanischen Eigenschaften des 28%-Chromstahles und bewirkt in der 4 N Lösung Bildung von Lochfraß an der Grenzfläche sigma-Phase/Ferrit. Die Bildung von Lochfraß konnte eindeutig auf Chrom- und Molybdänverarmung in der'Ferritmatrix zurückgeführt werden.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Scanning electron microscope images are presented of mica surfaces treated with an initiator and heated in the presence of styrene to obtain a grafted polymer. These images show “droplets” of size corresponding to that of individual polystyrene molecules. Other experimental evidence is presented which suggests that the droplets are indeed individual molecules. The images are believed to be the first ever obtained of individual, “tethered” synthetic polymer molecules.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 1143-1143 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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