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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 1503-1513 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A rapid method for determining the molecular weight distribution of polymers has been the aim of polymer chemists for a long time. The method presented here requires less than two hours, including dissolution of the polymer. It is an extension of a photoelectric turbidimetric technique presented by Taylor and Tung in 1961. The equipment has been completely redesigned and presently consists of a copper block containing a turbidity cell, optical system and attendant electronic circuitry for measuring relative changes in turbidity of polymer solutions as a function of temperature. An X-Y recorder is used to plot turbidity versus temperature. A parameter determined from the plot is correlated with a measure of molecular weight distribution determined on known samples for each type polymer by another means. Based on this correlation unknown samples may be analyzed. The instrument is easy to operate and has shown excellent stability over a two year period. Polymers studied by this technique include ethylene-propylene copolymer (EPR), polypropylene, polyethylene, and butyl, however, the only results to be reported here are those on ethylene-propylene copolymer.
    Additional Material: 11 Ill.
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  • 2
    ISSN: 0948-1907
    Keywords: Permalloy ; MOCVD ; Ferromagnetic thin films ; Magnetoresistance ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Thin films of elemental iron and nickel, plus a wide composition range of iron-nickel alloys, have been deposited by atmospheric pressure metal organic chemical vapor deposition at a growth temperature of 200°C, using iron pentacarbonyl and nickel tetracarbonyl as the source precursors. Detailed magnetoresistance measurements of the permalloy layers showed that the maximum value of magnetoresistance occurred at a composition of approximately 90 % Ni10 % Fe, and the maximum sensitivity occurred at approximately 80 % Ni20 % Fe, in accordance with literature values. In addition, both the application of an 80 mT magnetic field during deposition and the annealing of samples at temperatures higher than the growth temperature of 200°C improved the magnetic properties.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electroanalysis 7 (1995), S. 166-177 
    ISSN: 1040-0397
    Keywords: Zinc ; Complexation ; Seawater ; Rainwater ; Pseudopolarogram ; Trace metal ; Voltammetry ; Square wave anodic stripping voltammetry ; Complexometric titration ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A novel electrochemical method is described for the examination of metal-organic complexation in natural waters. The technique is based upon the comparison of square wave anodic stripping voltammetry (SWASV) ‘pseudopolarograms’ (current vs. deposition potential plots) for natural samples with those obtained for metal complexation with selected ‘model’ binding ligands at constant ionic strength. For electrochemically active zinc species in seawater, the pseudopolarogram approach allowed the estimation of thermodynamic stability constants (KML) within a stability constant window of approximately 104-106 M-1 up to ≥ 1015 M-1. For a natural rainwater sample, the pseudopolarogram indicated only one zinc class, probably a mixture of ‘free’ and/or inorganically complexed species. In an application to a coastal seawater sample, three species were identified: (1) weakly complexed, log KZnL = 4.14 ± 0.92 M-1; (2) moderately complexed, log KZnL = 7.77 ± 0.62 M-1; (3) strongly complexed, log KZnL = 11.45 ± 0.95 M-1. Results are compared to those obtained using complexometric titration with SWASV at a thin mercury film-glassy carbon rotating disk (TMF-GCRD) electrode. The latter detected a single strong complexing ligand (or ligand class), with [L′] = 15.25 ± 0.04 nM and log K′ZnL ≥ 10.9 M-1.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 31 (1986), S. 1155-1167 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dielectric spectroscopy was used to monitor the curing process of two epoxy resin systems. The basic system (system I) consisted of DGEBA (a difunctional epoxy) and a polyamide in a 50-phr mixture. In addition, a comparative analysis was performed on a high-performance resin system (system II) used primarily in unidirectional composite applications. This system contained TGDDM (a tetrafunctional epoxy) and DDS (a tetrafunctional amine) in a 25-phr mixture. The dielectric data were obtained using a simple yet functional sample cell electrode designed and constructed in the laboratory. For system I, isothermal dielectric data were used to determine apparent activation energies for the temperature range from 22 to 70°C. The data showed that the activation energy was a function of temperature and increased as the temperature of the cure increased. This indicated that the reaction mechanism was also a function of temperature. For system II, data were collected between 140 and 190°C and an overall activation energy for that temperature range was determined. The overall activation energies for both systems, calculated using dielectric spectroscopy, compared favorably to those obtained using differential scanning calorimetry. Also, using a wider frequency range (240 Hz to 2 MHz), Argand diagrams were constructed and modeled with the Cole-Cole empirical equation for systems with a distribution of relaxation times. This justified the calculation of average relaxation times, which could then be related to the bulk physical properties of the polymer, such as viscosity. Modified Argand diagrams, where ε″ is plotted against ε′ at one frequency as a function of time, were also constructed, which aided in the understanding of the curing processes for these thermosetting systems.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 1 (1992), S. 299-308 
    ISSN: 1057-9257
    Keywords: LPCVD ; Tantalum pentoxide ; High dielectric constant ; ULSI devices ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: A laminar flow low-pressure chemical vapour deposition (LPCVD) system (LAM IntegrityTM) has been used to deposit tantalum pentoxide (Ta2O5) from Ta(OEt)5 films in the presence of oxygen (O2) at 470 °C at a typical deposition rate of 4 nm min-1. Uniformities of 〈1.5% (SD 1σ) over a 150 mm silicon substrate were obtained. The layers were annealed under different conditions. It was discovered that the films did not change their stoichiometry as determined by Rutherford backscattering (RBS). The as-deposited films were amorphous but became crystalline (β-Ta2O5) at temperatures 〉 700 °C. The transmission electron microscopy (TEM) results on crystallisation behaviour were supported by X-ray diffraction data. The electrical properties of the Ta2O5 films have been characterised using MIS (metal/insulator/silicon) capacitor structures. Leakage values of 〈10-6 A cm-2 at 6 MV cm-1 equivalent applied electric field and breakdown strengths of 〉7 MV cm-1 at 1.6 μA were obtained for annealed layers. Compound dielectric constants (native silicon oxide thickness of about 2.5 nm plus Ta2O5 of various thicknesses) between 14 and 〉30 have been measured. The electrical properties reveal the potential use of Ta2O5 as a storage capacitor dielectric in 64 and 256 Mbit DRAM (dynamic random access memory) devices.
    Additional Material: 13 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 5 (1995), S. 163-175 
    ISSN: 1057-9257
    Keywords: ULSI ; high dielectric constant ; metal oxides ; deposition ; annealing ; characterisation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Flims of metal oxides, such as Ta2O5, Nb2O5, Al2O3, HfO2, ZrO2 and TiO2 have been fabricated by use of different precursor materials, deposition techniques and annealing techniques. Several analytical methods were applied to study the layers. New data of fundamental properties of these metal oxides are reported and related to practical features that are of importance in device design and manufacturing of advanced, highly integrated devices. This overview may facilitate the choice of an optimal combination of precursor material, deposition technique and corresponding annealing procedure for a specific application of these metal oxide films in microelectronics.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Biomaterials 5 (1994), S. 109-115 
    ISSN: 1045-4861
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The purpose of this study was to examine the effects of particles, derived from metals commonly used in joint prostheses, on chondrocyte proliferation, metabolism, and morphology in vitro. Chondrocyte viability was influenced by the type and concentration of metal particle added. Cobalt was toxic to chondrocytes at all particle concentrations (0.83-0.000083%, v/v), whereas the chromium, titanium and titanium-aluminum particles only effected chondrocyte viability at high concentrations. The metabolic response of chondrocytes to particulate debris as assessed by caseinase, collagenase, and hexosaminidase activities were variable at low concentrations but were always reduced at high concentrations (0.83% v/v). Prostaglandin E2 levels in the medium showed a steady increase when particle load increased, except in the medium of chondrocytes exposed to titanium-aluminum. Scanning electron microscopy of chondrocytes exposed to titanium showed ruffled cell borders and frequent membrane blebbings. This was in contrast to chondrocytes exposed to cobalt, where the crenated appearance indicated cell death, and titanium-aluminum, where the cells appeared quiescent. These findings show that metal particles alter chondrocyte viability and metabolism and suggest that particulate debris may influence the integrity and stability of articular cartilage following hemiarthroplasty. © 1994 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
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  • 8
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 9
    ISSN: 0006-3525
    Keywords: short duplex DNA ; sequence-dependent hybridization reactions ; sequence-dependent melting stability ; oligomers ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Many important applications of DNA sequence-dependent hybridization reactions have recently emerged. This has sparked a renewed interest in analytical calculations of sequence-dependent melting stability of duplex DNA. In particular, for many applications it is often desirable to accurately predict the transition temperature, or tm, of short duplex DNA oligomers (∼ 20 base pairs or less) from their sequence and concentration. The thermodynamic analytical method underlying these predictive calculations is based on the nearest-neighbor model. At least 11 sets of nearest-neighbor sequence-dependent thermodynamic parameters for DNA have been published. These sets are compared. Use of the nearest-neighbor sets in predicting tm from the DNA sequence is demonstrated, and the ability of the nearest-neighbor parameters to provide accurate predictions of experimental tm's of short duplex DNA oligomers is assessed. © 1998 John Wiley & Sons, Inc. Biopoly 44: 217-239, 1997
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 2191-2193 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
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