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  • Articles  (2,034)
  • Polymer and Materials Science  (2,034)
  • 1980-1984  (1,207)
  • 1970-1974  (827)
  • 1
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 2817-2834 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal degradation behavior of poly(1,3-phenylene isophthalamide) and poly(chloro-2,4-phenylene isophthalamide) was investigated with the aid of some appropriate model compounds. The pyrolysis products of these materials were identified by gas chromatography (GC), gas chromatography/Fourier transform infrared spectroscopy (GC/FT-IR), and gas chromatography/mass spectrometry (GC/MS). The residual chars were characterized by IR spectroscopy. Thermogravimetric analysis (TGA) was applied to study the effect of end-group concentration on the degradation characteristics of the two polyamides. Kinetic parameters that describe the thermal degradation of the polyamides were also evaluated by TGA. The results of this investigation suggest that the thermal decomposition of these aromatic polyamides involves homolytic as well as hydrolytic cleavages of the amide units.
    Additional Material: 13 Ill.
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  • 3
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyperfluorobut-2-yne is prepared by a fluoride ion-induced polymerization of hexafluorobut-2-yne. The mass spectrum indicates a regular fragmentation pattern but the ESCA spectrum establishes the structure as a polyene, rather than a crosslinked system, and the occurrence of a shake-up peak assists in this assignment.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 79-88 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: There are two major fire processes, an understanding of which is essential for effective fire safety design: (1) the conditions under which a combustible material may become involved in flaming combustion, and (2) the rate at which such a material, once involved, will provide an output of heat, smoke, toxic gases, etc., which can endanger people and property. The first process may be regarded as covering both ignition and spread of fire on materials; its complement is the way in which fire may become extinguished. It is necessary for such processes to bring in a characteristic of the basic combustion reaction which, directly or indirectly, expresses the reactivity of the combustion process. Thus pilot ignition is usually associated with an approximate surface fuel temperature. More basically, it is associated with a critical flow rate of volatiles and a critical heat loss from the flame, the latter being influenced by ambient oxygen and temperatures conditions as well as heat lost and gained by the fuel itself. The most important factor governing the production of dangerous product is the rate at which volatiles first (fuel controlled fires) and later air (air controlled fires) are fed into the flames. The reactivity is of less importance, although it may be one of the factors which control combustion efficiency. In general, the more efficient is the combustion the more heat is produced, but the less smoke and toxic gases are produced. Some of the main advances in the above areas are reviewed in this paper.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 3543-3553 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An analytical procedure for determining the antioxidant (i.e., Akroflex CD) content in neoprene rubber has been developed. The method is based on the infrared absorption analyses of chloroform extractables from the cured rubber at 1600 cm-1 and 1300 cm-1. Good agreement is found between these two independent sets of measurements. In an attempt to elucidate the antioxidant loss mechanism found with neoprene, thermal aging studies were carried out over the temperature range of 80°-200°C. Using the infrared analytical procedure, antioxidant loss rates at the different temperatures were established. The activation energy value (5.1 kcal/mole) for the loss rate as well as other aging data suggest that the antioxidant is lost by a diffusion mechanism.
    Additional Material: 9 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 509-519 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The deterioration of polyolefin, poly(ethylene terephthalate), and polyamide films under soil burial conditions extending up to 32 months has been investigated. Based on changes in their elongation at break, the films can be ranked in order of increasing sensitivity to degradation: Polyester ≃ polypropylene 〈 low-density polyethylene ≃ high-density polyethylene 〈 nylon 6.6. The degraded nylon 6.6 and polyethylene films were characterized by infrared and luminescence spectroscopy and scanning electron microscopy, as well as by wet analysis for hydroperoxides. From a comparison with the well-known oxidative sensitivity of nylon 6.6 in oxygenated water at slightly elevated temperatures, the rapid deterioration of nylon 6.6 film during soil burial was also concluded to be an oxidative process. The somewhat smaller, but significant, embrittlement of the polyethylenes studied could not be simply explained by thermal oxidation (with only trace oxidation products detectable) or microbiological attack (deterioration being unaffected by surface activation to enhance wettability).
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 3353-3360 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Two independently derived distribution function methods validate both the calibration curve and the dispersion correction of the “effective linear calibration” method used in gel permeation chromatography (GPC). Experimental conditions are specified for making the method more useful by permitting linear extrapolation of the calibration line, \documentclass{article}\pagestyle{empty}\begin{document}$ V_R = C_1 + C_2 \log M, $\end{document} and for using a minimum number of standards. The independent methods quantitatively relate known differential of integral distribution functions for standard samples to their respective chromatograms. As such, they are useful calibration methods also, but are limited in scope and range.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 269-282 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The development of gel permeation chromatography (GPC) has provided a convenient tool for the rapid determination of molecular weight distribution. The question has arisen as to the suitability of the method for specification purposes. The present work, suggested by the Naval Air Systems Command, represents an attempt to assess the precision of the method through a series of tests carried out by a number of laboratories using identical procedures on the same samples. Ten laboratories agreed to take part. Naval Ordnance Station, Indian Head, worked out standard conditions for operation of the chromatograph, for calibration of the columns, and for analysis of the GPC curves. Two samples of polystyrene were used by the various organizations for calibration of their instruments. Number-average molecular weight, heterogeneity index, and cumulative molecular weight distribution curves were determined on four samples of carboxyl-terminated polybutadiene (CTPB) and two samples of hydroxyl-terminated polybutadiene (HTPB), all unidentified except by letter code. All laboratories used identical directions for setting up CTPB and HTPB calibration curves which were based on curves determined from vapor-pressure osmometer molecular weights and GPC count numbers of fractionated material. Variation among the different laboratories was 0.15 in heterogeneity index, and a maximum of 1200 in molecular weight provided one aberrant set of values was eliminated. The six samples had heterogeneity indices from 1.15 to 1.54, while molecular weight varied from approximately 3000 to 6000. The average coefficient of variation of the molecular weight values was 6.2 ± 0.7%, which is quite acceptable. Variation in heterogeneity index was too great for specification purposes when considered among the different laboratories, but may be sufficiently good when measured by any one laboratory.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 321-334 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Optical-absorption, fluorescence, and Raman spectra for solutions, suspensions, and precipitates of poly(1,6-di-p-toluene sulfonoxy-2,4-hexadiyne) in and from nitrobenzene, acetone, and chloroform are presented. These are interpreted in terms of the occurrence of two forms of the polymer chain; a quasicrystalline form with properties close to those of single crystal polymer and a chain-extended form occurring in solution and colloidal particles, with an absorption energy of about 2.5 eV (20,000 cm-1). No evidence is found for the presence of very short polymer chains in partially polymerized monomer at low conversion. The relationship of these results to those for deformed single crystals is briefly discussed.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 169 (1973), S. 177-189 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die elektroinitiierte Polymerisation von N-Vinylcarbazol (VCZ) wurde in Aceton bei 25°C mit Zinkbromid als Katalysator unter Verwendung von Platinelektroden eingehend untersucht. Die Polymerisationsgeschwindigkeit erwies sich als direkt abhängig von der Stromstärke, der Zinkbromid-Konzentration und dem anfänglichen Wassergehalt des Solvens.Die Molekulargewichte der entstandenen Polymeren (1000-6000) sind unabhängig von der Stromstärke, der Zinkbromid-Konzentration und dem Umsetzungsgrad des Monomeren zum Polymeren, werden jedoch beeinflußt durch Wasser, die Monomerkonzentration und das Elektrodenmaterial. Die chemische Zusammensetzung der Polymeren ändert sich nicht mit der Stromstärke, der Zinkbromid-Konzentration, dem Umsetzungsgrad und dem Elektrodenmaterial. Sie ändert sich jedoch ein wenig mit dem Wassergehalt des Acetons.
    Notes: The electroinitiated polymerization of N-vinylcarbazole (VCZ) in acetone solvent at 25°C with zinc bromide, as catalyst, and platinum electrodes was investigated in detail. The polymerization rate was found to be directly dependent on current strength, zinc bromide concentration and the initial water content of the solvent.The molecular weights of the formed polymers (1000-6000) are independent of current strength, zinc bromide concentration and degree of conversion of monomer to polymer, but are affected by water, monomer concentration, and by the type of electrodes used. The chemical composition of the polymer is invariant with current strength, zinc bromide concentration, degree of conversion, and electrode material but does vary slightly with the water content of acetone.
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