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  • Polymer and Materials Science  (9)
  • Atomic, Molecular and Optical Physics  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 184 (1991), S. 99-110 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Aus einem phenolischen Copolymeren bekannter Zusammensetzung und verschiedenen nicht ionischen Homopolymeren (PVP, PEO, PVA) sowie Polyelektrolyten wie PAA und PEI wurden in Lösung Mehrkomponenten-Interpolymerkomplexe hergestellt. Die Bildung dieser Komplexe wurde mit verschiedenen Methoden, wie Viskosimetrie, Potentiometrie, Konduktometrie und IR-Spektroskopie untersucht. Es wird ein Schema zur Erklärung der Art der Wechselwirkung zwischen den verschiedenen Polymerkomponenten vorgeschlagen.
    Notes: Multicomponent interpolymer complexes have been prepared by interacting a phenolic copolymer of known composition with several non-ionic homopolymers, e.g., PVP, PEO, PVA and polyelectrolytes, such as PAA and PEI. The formation of these complexes has been studied by several techniques, such as viscometry, potentiometry, conductometry, and IR spectra. A scheme has been presented to explain the mode of interaction of the various component polymers.
    Additional Material: 4 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 200 (1992), S. 1-13 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Poly(methacrylsäure-co-methacrylamid) und Poly(acrylsäure-co-acrylamid) wurden hergestellt und mit bekannten Methoden charakterisiert. Die jeweiligen Comonomereinheiten der beiden Copolymeren können durch Wasserstoffbrückenbindung und Ion-Dipol-Wechselwirkungen Komplexe bilden. Die nicht-komplexierten Einheiten der Intercopolymerkomplexe können noch entweder mit anderen Homopolymeren wie Poly(N-vinylpyrrolidon) oder Poly(oxyethylen) wechselwirken oder mit Übergangsmetallionen drei- und vierkomponentige Komplexe bilden. Die Bildung solcher Komplexe wurde mittels Viskosimetrie, Konduktometrie, Potentiometrie und IR- und UV-Spektroskopie untersucht.
    Notes: Poly(methacrylic acid-co-methacrylamide) and poly(acrylic acid-co-acrylamide) have been synthesized and characterized by known methods. The respective comonomer units of the two copolymers enter into complex formation through hydrogen bonding and ion-dipole interactions. The unreacted units in the intercopolymer complex also interact with homopolymers such as poly(N-vinylpyrrolidone) and poly(oxyethylene) as well as transition metal ions to form three and four component intermacromolecular complexes. Formation of these complexes could be shown through several experimental techniques, e.g. viscometry, conductometry, potentiometry, IR and UV spectrophotometry.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 23 (1983), S. 1-26 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new density-functional equation is suggested for the direct calculation of electron density ρ(r) in many-electron systems. This employs a kinetic energy functional T2 + f(r)T0, where T2 is the original Weizsäcker correction, T0 is the Thomas-Fermi term, and f(r) is a correction factor that depends on both r and the number of electrons N. Using the Hartree-Fock relation between the kinetic and the exchange energy density, and a nonlocal approximation to the latter, the kinetic energy-density functional is written (in a.u.) \documentclass{article}\pagestyle{empty}\begin{document}$$ t[\rho] = {\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 4}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{$4$}}\nabla ^2 \rho + {\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 8}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{$8$}}(\nabla \rho \cdot \nabla \rho)/\rho + C_k f({\bf r})\rho ^{5/3}, $$\end{document} where \documentclass{article}\pagestyle{empty}\begin{document}$ C_k = {\raise0.7ex\hbox{$2$} \!\mathord{\left/ {\vphantom {2 {10}}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{${10}$}}(3\pi ^2)^{2/3} $\end{document}. Incorporating the above expression in the total energy density functional and minimizing the latter subject to N representability conditions for ρ(r) result in an Euler-Lagrange nonlinear second-order differential equation \documentclass{article}\pagestyle{empty}\begin{document}$$ \left[{ - {\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 2}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{$2$}}\nabla ^2 + v_{{\rm nuc}} ({\bf r}) + v_{{\rm cou}} ({\bf r}) + v_{XC} ({\bf r}) + {\raise0.7ex\hbox{$5$} \!\mathord{\left/ {\vphantom {5 3}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{$3$}}C_k g({\bf r})\rho ^{2/3}} \right]\phi ({\bf r}) = \mu \phi ({\bf r}) $$\end{document} where μ is the chemical potential, we have ρ(r) = |φ(r)|2, and g(r) is related to f(r). Numerical solutions of the above equation for Ne, Ar, Kr, and Xe, by modeling f(r) and g(r) as simple sums over Gaussians, show excellent agreement with the corresponding Hartree-Fock ground-state densities and energies, indicating that this is likely to be a promising method for calculating fairly accurate electron densities in atoms and molecules.
    Additional Material: 12 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 22 (1982), S. 871-888 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In presence of external electric and magnetic fields, the Schrödinger equation for many-electron systems is transformed into a continuity equation and an Euler-type equation of motion in configuration space. Then, using the natural-orbital Hamiltonian, as defined by Adams, the two fluid-dynamical equations are derived in the three-dimensional space. This generates a “classical” view of such quantum systems, corresponding to an MCSCF wave function: The many-electron Schrödinger fluid consists of individual fluid components, each corresponding to a natural orbital and having its own charge density and current density. The local observables, viz., the net charge density and net current density, are obtained by merely summing over the natural orbitals, with the occupation numbers as weight factors; but, the net velocity field cannot be so obtained. Further, although each fluid component moves irrotationally in the absence of a magnetic field, the net velocity field is not irrotaional. The irrotational character of each velocity component is destroyed by rotation of the nuclear framework of the system while electron spin introduces an additional term, the spin magnetization moment, into each component current density. The physical significance of the fluid-dynamical equations as well as their advantages and disadvantages are discussed.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 1125-1136 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Fired clay membranes were prepared from montmorillonite clay and also by incorporating protein (lysozyme) and nylon (copolymer of 6-amino caproic acid) to clay followed by firing these membranes at different temperatures for different durations of time. Osmotic behaviors of the membranes were studied, and the results were correlated to the porosity determined by scanning electron microscope. Reverse osmosis parameters, namely, the reflection coefficient, solute permeability, and rejection coefficient, of the membranes were determined from osmosis experiments. Rejection coefficients as determined from reverse osmosis were compared with those obtained from osmosis experiments.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 331-339 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sorption characteristics of vapors of pure hydrocarbon and their binary mixtures in low-density polyethylene were studied under various conditions of temperature and pressure. A new apparatus devised and utilized for the determination of composition of sorbed vapor in case of binary mixtures is described. The study demonstrates the effect of the presence of one component within the polymer on the sorption of another and also the occurrence of selectivity in sorption.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 40 (1990), S. 1049-1052 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 10 (1972), S. 2305-2309 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1275-1284 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An investigation of steady state and transient photoconductivity in films of poly-(N-vinylcarbazole) equipped with SnO2 and metal electrodes is described. The studies have shown that photoinduced charge transfer, leading to hole injection into the polymer film, takes place with photons of energy greater than 1.8-1.9 eV. Dark conductivity studies on samples equipped with grounded guard rings have shown that carriers originating in the bulk of the polymer film dominate the dark current when the metal electrode is at negative bias. Thermionic hole emission from the SnO2 electrode is not observed.
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 143 (1971), S. 181-187 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Eine neue, schnelle Methode, nämlich die Technik der Gaschromatographie, fand zur Bestimmung des Löslichkeitsparameters von Polyäthylen Anwendung. Zwischen den berechneten Mengen, die das Polymere von verschiedenen reinen Komponenten aufgenommen hat, und den experimentell bestimmten Mengen besteht ein logarithmischer Zusammenhang.
    Notes: A new and quick method, namely, the gaschromatographic technique, has been used to determine the solubility parameter of polyethylene. The calculated quantities of sorption of various pure components in polymer bears a logarithmic relationship to the experimental values.
    Additional Material: 4 Ill.
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