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  • Polymer and Materials Science  (35)
  • Analytical Chemistry and Spectroscopy  (34)
  • General Chemistry  (5)
  • Wiley-Blackwell  (74)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 212 (1993), S. 13-18 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die elektrische Leitfähigkeit (σ) von Cellulose-HYPHAN® und seinen Komplexen mit Cr3+, Mn2+, Mo5+ und Hg2+ wurde im Temperaturbereich 25-510°C bestimmt. Die Aktivierungsenergie wurde aus der Abhängigkeit von log σ von der reziproken Temperatur berechnet. Die Ergebnisse zeigen, daß die Leitfähigkeit mit steigender Temperatur zunimmt und dabei zwei Maxima durchläuft. Das erste Maximum läßt sich dem Wassergehalt zuordnen, während das zweite mit dem thermischen Abbau der Cellulose-Kette zusammenhängt. Die Werte der Aktivierungsenergie lassen darauf schlieäen, daß sich beim Erhitzen die Halbleitereigenschaften der Komplexe verbessern.
    Notes: The electrical conductivity, σ, of cellulose HYPHAN® and its complexes with Cr3+, Mn2+, Mo5+ or Hg2+ was measured from room temperature to 510°C. The activation energy, ΔE, of the samples was calculated from log σ against 1/T curves. The results show that the electrical conductivity increases by temperature with two maximum peaks. The first peak is attributed to the moisture content, while the second one is attributed to the thermal degradation of the cellulose chain. The values of the activation energy indicate that the samples change from low semiconductor to high semiconductor property with heating.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 17 (1996), S. 683-691 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of parameters such as styrene dilution and active site concentration on the polymerization of styrene in the presence of a di-tert-butyl nitroxide adduct (A-T) was examined. It is confirmed that the rate of styrene polymerization is independent of A-T concentration, with no monomer dilution effect. An increase in radical concentration generated in the medium leads to faster propagation, but the molecular weight of the polymers formed is alway controlled by the A-T concentration.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 18 (1994), S. 9-16 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Burn tests were conducted on a number of Christmas trees commonly used in typical households. Trees were kept in room conditions for several weeks to dry out. Burn tests were also conducted on fresh and almost fresh trees to compare their burning behaviors wilth those of dry trees. Two trees were moistened and wetted prior to burn to observe the effects of water on burning of dry trees. The foremost objective of this work was to quantitatively demonstrate the potential fire hazard of Christmas trees by measuring the rate of heat release and room temperature during the burn.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 16 (1992), S. 159-167 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An investigation has been carried out of the limiting oxygen index (LOI) test. A review of the literature shows that, although there is abundant information on the test, it is not clear that its results correlate well with those of any other test, or indeed with those of real fires. Theoretical considerations indicate that the test could be improved by using it with bottom ignition rather than with the standard top ignition. A number of materials were tested in the cone calorimeter and in the LOI, and various correlations were attempted. In general, correlations between some of the cone calorimeter properties measured and the inverse of the LOI made sense. These correlations were not, however, sufficiently sensitive, even when investigating small effects on a single base polymer system, to justify using the LOI as a proxy for the cone in any way. The LOI is likely to continue to be used extensively. This work suggests that quality control and, possibly, mechanistic or other flame-retardant additive studies, are its only applications where the results can be justified.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 40 (1989), S. 708-710 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die durch Cerionen initiierte Pfropfung von Methylmethacrylat auf Stärke wurde untersucht, wobei die nicht absorbierten Cerionen entweder im Substrat blieben oder entfernt wurden. Der Pfropfgrad, die Molekülmasse der gepfropften Ketten und die Anzahl der Pfropfungen wurden in Abhängigkeit von der Konzentration der Cerionen bestimmt. Auf Basis der erhaltenen Ergebnisse wird der Mechanismus der Pfropfreaktion diskutiert.
    Notes: Methyl methacrylate was grafted onto starch by the ceric ion method with and without removing of the unabsorbed ceric ions. Graft level, molecular weight of the grafted chains, and number of the grafted chains were measured in dependence on ceric ion concentration. On base of the results the mechanism of the grafting reaction is discussed.
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 38 (1987), S. 443-446 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Infrarotspektren von Poly(methylmethacrylat)-Probenn die mit verschiedenen lumineszierenden Substanzen dotiert wurden, weisen außer beim β-Naphthol keine wesentlichen Änderungen der Lage und Intensität der Absorptionsbanden auf. Daher wird angenommen, daß zwischen den meisten Dotierungsmitteln und PMMA keine Wechselwirkung besteht, während beim β-Naphthol zwischen benachbarten Molekülen in der Polymermatrix Wasserstoffbindungen auftreten.
    Notes: The infrared spectra of poly(methyl methacrylate) samples doped with different luminescent materials show no drastic changes in the position and intensity of the absorption bands, except in case of β-naphthol. From this it is supposed that there is no interaction between the dopant and PMMA with most of the investigated materials, while with β-naphthol hydrogen bonding between adjacent molecules in the polymer matrix is observed.
    Additional Material: 5 Ill.
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  • 7
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Substanzcopolymerisation von Methylmethacrylat und Chromacrylat wurden neue halbleitende Copolymere erhalten. Das chemische Reaktionsschema wird diskutiert. Dichte und Harte der Proben nehmen mit steigendem Chromgehalt ab. Im Infrarotspektrum wurde eine Verbreiterung der Carbonylbande bei 1 710 cm-1 beobachtet, was auf eine mogliche Koordination der C=O-Gruppe mit Chromionen hinweist. Die elektrische Leitfahigkeit der Proben nimmt mit steigendem Chromacrylatgehalt zu. Der Einfluß einer γ-Bestrahlung auf die elektrische Leitfahigkeit der Copolymere wurde untersucht.
    Notes: New semiconducting copolymers were prepared by bulk copolymerization of methyl methacrylate with chromium acrylate. The pattern of the chemical reactions is discussed. The density and hardness of the samples decrease with increase of the chromium content. I n the infrared spectrum broadening of the carbonyl band a t 1710 cm-l is observed, which indicates the possibility of coordination of the C=O group with the chromium ion. The electrical conductivity of the samples increases with increase of chromium acrylate content. The effect of y-irradiation on the electrical conductivity of the copolymers was studied.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 40 (1989), S. 126-128 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Verfahren zur Pfropfcopolymerisation von Acrylnitril auf gebleichte Holocellulose, wobei die nicht adsorbierten Cerionen aus dem Polymerisationssystem entfernt werden, wird beschrieben. Mit dieser Methode werden höhere Pfropfgrade und höhere Pfropfausbeuten erreicht als bei der kontinuierlichen Initiierung.
    Notes: The graft copolymerization of acrylonitrile onto bleached holocellulose using an initiation procedure in which the unadsorbed ceric ions are removed from the polymerization system is reported. With this method higher graft levels and higher efficiency of grafting is achieved than with the continuous initiation method.
    Additional Material: 3 Ill.
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  • 9
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 472-473 
    ISSN: 0009-286X
    Keywords: Fluiddynamik ; Stoffübergang ; hochviskose Systeme ; Siebboden ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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