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  • Polymer and Materials Science  (1)
  • 1975-1979  (1)
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  • 1
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die radikalische Copolymerisation von Methylmethacrylat (MMA) und Allylmethacrylat (AMA) wurde studiert. Die Reaktionen wurden mit Azoisobutyronitril (AIBN) in Anwesenheit von ZnCl2 initiiert. Mit zunehmender ZnCl2-Konzentration nimmt die Copolymerisationsgeschwindigkeit zu, und die Copolymerisationsparameter bleiben nicht konstant. MMA und AMA bilden EDA-Komplexe mit ZnCl2. Diese Komplexbildung erklärt unsere Ergebnisse.
    Notes: Radical copolymerization of methyl methacrylate (MMA)-allyl methacrylate (AMA) in the presence of zinc chloride, using azoisobutyronitrile (AIBN) as initiator has been carried out. The copolymerization rate increases with the concentration of ZnCl2 and the reactivity ratios are modified by the concentration of ZnCl2 which is explained by the different tendency towards the formation of complexes between MMA and AMA with ZnCl2.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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