ISSN:
0009-2940
Schlagwort(e):
Planar-tetraccordinate carbon
;
μ-Acetylide complex
;
μ-Aryl cyanide complex
;
Zirconocene cation
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The planar-tetracoordinate carbon compound 4 exchanges the bridging μ-(η1-C:η2-C,C)-2-butyne ligand for p-tolunitrile in dichloromethane at 90°C to yield the [μ-(η1-N:η2-C,N)-aryl cyanide]dizirconium cation complex 2a. X-ray diffraction revealed an aza-allenyl-type character of the RCNZr moiety in this thermodynamically favored (μ-nitrile)zirconium cation complex.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19951281013
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