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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 1025-1035 
    ISSN: 0887-6266
    Keywords: polymer thin films ; thermosets ; microelectronics ; moisture ; physical aging ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In polymers for microelectronics applications, moisture is known to have a deleterious effect upon device reliability. In this paper, the moisture transport behaviors of a newly developed family of all-aromatic and aromatic/aliphatic copolyester thermosetting films were described. The moisture uptake as a function of temperature, relative humidity, sample thickness, and processing conditions were presented via conjugate moisture sorption tests.1 It was found that the post curing near but below Tg resulted in an increase in both total moisture uptake and diffusion coefficient due to the effect of physical aging and the generation of sample defect volume. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1025-1035, 1998
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 2207-2224 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis and structure of the p-hydroxybenzoic acid polymer is described. The polymer was successfully prepared from either the phenyl ester of p-hydroxybenzoic acid or from p-acetoxybenzoic acid. With highly purified acetoxybenzoic acid, single crystals of the polymer could be prepared. The structure of the polymer was determined and shown to consist of a double helix where the two chains are in a reversed head-to-tail order. The unit cell dimensions are: a = 17.8 Å and c = 18.4 Å, where c corresponds to the chain length with a repeat distance of three units. The mechanism of polymerization and formation of the single crystal is discussed. The polymer displays a reversible high-temperature crystalline transition at 325-360°C (not a melting point). The transition was characterized by differential thermal analysis, differential calorimetry, thermal expansion coefficient measurements, high-temperature x-ray scans, and dielectric constant determinations. Orientation of the polymer chains during fabrication and changes in the mechanism of oxidative degradation above the crystal transition are described.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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