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Effect of chemical structure and thermal history on the β transition of polystyrene and some substituted polystyrenes (1976)

Bach Van, Nguyen ; Noel, C.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 14 (1976), S. 1627-1636

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: DTA (differential thermal analysis) traces for various kinds of polystyrene and substituted polystyrenes, including bulk-polymerized, monodisperse, and isotactic samples, have been recorded below the glass temperature. It has been shown that the β transition is dependent upon polymer structural modification, traces of water or solvent, and sample thermal history. The experimental data presented here support the conclusion that the β transition is due to conformational changes involving backbone motions and phenyl ring reorientation.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1976.170140706

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