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  • AERODYNAMICS  (484)
  • Physics  (339)
  • 1980-1984  (822)
  • 1945-1949  (1)
  • 1935-1939
  • 1
    Electronic Resource
    Electronic Resource
    Spectroscopic studies of solutions, suspensions, and precipitates of poly(1,6-di-p-toluene sulfonyloxy-2,4-hexadiyne) (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 321-334 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Optical-absorption, fluorescence, and Raman spectra for solutions, suspensions, and precipitates of poly(1,6-di-p-toluene sulfonoxy-2,4-hexadiyne) in and from nitrobenzene, acetone, and chloroform are presented. These are interpreted in terms of the occurrence of two forms of the polymer chain; a quasicrystalline form with properties close to those of single crystal polymer and a chain-extended form occurring in solution and colloidal particles, with an absorption energy of about 2.5 eV (20,000 cm-1). No evidence is found for the presence of very short polymer chains in partially polymerized monomer at low conversion. The relationship of these results to those for deformed single crystals is briefly discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190212
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  • 2
    Electronic Resource
    Electronic Resource
    Aromatic polyamides. II. Thermal degradation of some aromatic polyamides and their model diamides (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 2817-2834 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal degradation behavior of poly(1,3-phenylene isophthalamide) and poly(chloro-2,4-phenylene isophthalamide) was investigated with the aid of some appropriate model compounds. The pyrolysis products of these materials were identified by gas chromatography (GC), gas chromatography/Fourier transform infrared spectroscopy (GC/FT-IR), and gas chromatography/mass spectrometry (GC/MS). The residual chars were characterized by IR spectroscopy. Thermogravimetric analysis (TGA) was applied to study the effect of end-group concentration on the degradation characteristics of the two polyamides. Kinetic parameters that describe the thermal degradation of the polyamides were also evaluated by TGA. The results of this investigation suggest that the thermal decomposition of these aromatic polyamides involves homolytic as well as hydrolytic cleavages of the amide units.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170191115
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  • 3
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    Advanced technology exhaust nozzle development (1983)
    In:  Other Sources
    Details
    Publication Date: 2019-06-28
    Description: The requirement for greater tactical aircraft operational capabilities has led to increasing research emphasis on the refinement of engine/airframe integration methods and exhaust nozzle flexibility. A major prospective advancement in the development of these capabilities takes the form of multifunctional exhaust nozzle systems with thrust reversal and thrust vectoring features, whose operation will be shared by both airframe and powerplant control systems. Attention is presently given to the two-dimensional convergent-divergent and single expansion ramp nozzle designs, with emphasis on the variable geometry mechanical systems by which they assume cruising flight, vectoring, and thrust reversal operations. The nozzles have been wind tunnel model-tested for the cases of the F-18 fighter and a supersonic cruise configuration concept.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 83-1286
    Format: text
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    NASA TECHNICAL REPORTS
  • 4
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    PAN AIR: A computer program for predicting subsonic or supersonic linear potential flows about arbitrary configurations using a higher order panel method. Volume 4: Maintenance document (version 1.1) (1981)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: The Maintenance Document is a guide to the PAN AIR software system, a system which computes the subsonic or supersonic linear potential flow about a body of nearly arbitrary shape, using a higher order panel method. The document describes the over-all system and each program module of the system. Sufficient detail is given for program maintenance, updating and modification. It is assumed that the reader is familiar with programming and CDC (Control Data Corporation) computer systems. The PAN AIR system was written in FORTRAN 4 language except for a few COMPASS language subroutines which exist in the PAN AIR library. Structured programming techniques were used to provide code documentation and maintainability. The operating systems accommodated are NOS 1.2, NOS/BE and SCOPE 2.1.3 on the CDC 6600, 7600 and Cyber 175 computing systems. The system is comprised of a data management system, a program library, an execution control module and nine separate FORTRAN technical modules. Each module calculates part of the posed PAN AIR problem. The data base manager is used to communicate between modules and within modules. The technical modules must be run in a prescribed fashion for each PAN AIR problem. In order to ease the problem of supplying the many JCL cards required to execute the modules, a separate module called MEC (Module Execution Control) was created to automatically supply most of the JCL cards. In addition to the MEC generated JCL, there is an additional set of user supplied JCL cards to initiate the JCL sequence stored on the system.
    Keywords: AERODYNAMICS
    Type: NASA-CR-3254 , NAS 1.26:3254 , D180-24910-4
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 5
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    A computational and experimental study of high Reynolds number viscous/inviscid interaction about a cone at high angle of attack (1980)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The flow over a 5 deg semi-angle cone at incidence in supersonic flow is studied as a model problem for the flow over aircraft forebodies. A computational method utilizing the conically symmetric Navier-Stokes equations is used to obtain theoretical flow results which are compared with experimental data from the Ames Research Center 6- by 6-Foot Wind Tunnel and with results from a cone model sting mounted on an F-15 aircraft. The computed results agree well with the wind-tunnel data but less well with the flight data. Modification of the algebraic turbulence model was necessary to reflect an apparent lower turbulence level in flight than was present in the wind tunnel.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 80-1422 , Fluid and Plasma Dynamics Conference; Jul 14, 1980 - Jul 16, 1980; Snowmass, CO
    Format: text
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    NASA TECHNICAL REPORTS
  • 6
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    Flight experiments with a slender cone at angle of attack (1981)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: The three-dimensional leeward separation about a 5 deg semi-angle cone at an 11 deg angle of attack was investigated in flight, in the wind tunnel, and by numerical computations. The test conditions were Mach numbers of 0.6, 1.5, and 1.8 at Reynolds numbers between 7 and 10 million based on free-stream conditions and a 30-inch wetted length or surface. The surface conditions measured included mean static and fluctuating pressures; skin friction magnitudes and separation line positions were obtained using obstacle blocks. The mean static pressures from flight and wind tunnel were in good agreement. The computed results gave the same distributions, but were slightly more positive in magnitude. The experimentally measured primary and secondary separation line locations compared closely with computed results. There were substantial differences in level and in trend between the surface root-mean-square pressure fluctuations obtained in flight and in the wind tunnel, due, it is thought, to a relatively high acoustic disturbance level in the tunnel compared with the quiescent conditions in flight.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 81-0337 , Aerospace Sciences Meeting; Jan 12, 1981 - Jan 15, 1981; St. Louis, MO
    Format: text
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    NASA TECHNICAL REPORTS
  • 7
    Electronic Resource
    Electronic Resource
    Lyotropic mesomorphic formation of cellulose in trifluoroacetic acid-chlorinated-alkane solvent mixtures at room temperature (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1231-1236 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Mixtures of trifluoroacetic acid (TFA)-1,2-dichloroethane (1,2-DCE); TFA-dichloromethane (CH2Cl2); and TFA-trichloromethane (CHCl3) are excellent cellulose solvents at room temperature. TFA-1,2-DCE and TFA-CH2Cl2 are superior to pure TFA. Lyotropic cellulose mesophases were obtained in (20% w/v) solutions of cellulose in these solvent mixtures. The optical and optical rotatory powers of the solutions suggest that the lyotropic mesophase of cellulose is cholesteric. This implies that cellulose molecules are arranged in helical form in these solvent systems.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190806
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  • 8
    Electronic Resource
    Electronic Resource
    Microphase separation in sulfonated polystyrene ionomers (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 1503-1509 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Small- and wide-angle x-ray scattering results for a series of un-neutralized and neutralized sulfonated polystyrenes are presented for the range of sulfonation from 0 to 7.26 mol %. From the small-angle scattering it is shown that above the 3 mol % level for both the zinc and sodium salts, a Bragg spacing (37 Å) and diameter (6.9-8.4 Å) of the scattering unit can be calculated. When the concentration of salt is increased, there is no appreciable change in the latter two measurements. The wide-angle data indicate that the cations do not influence to any large extent the basic intramolecular and intermolecular structure of polystyrene. All the data are consistent with the onset of clustering above a critical ion concentration.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.180200815
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  • 9
    Electronic Resource
    Electronic Resource
    Structure and morphology of heavily deformed single crystals of a polydiacetylene. I. Electron microscopy and x-ray diffraction (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 293-305 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The structure and morphology of heavily deformed single crystals of a diacetylene polymer have been studied using a combination of x-ray diffraction and electron microscopy. Crystals have been deformed by both rolling and hammering. The crystals remain intact during deformation and can be reduced in thickness by a factor of over 5 in directions perpendicular to their chain axes. It is found that the chain orientation is maintained during both hammering and rolling. A greenish-colored surface skin develops during both types of deformation but the structure of the interior of the crystals depends upon the type of deformation employed. The interior of the hammered crystals consists of crystal blocks ca. 50 μm thick formed by cleavage perpendicular to the chain direction whereas the rolled crystals tend to be fibrous with no evidence of molecular fracture. The possible deformation mechanisms which have given rise to the different structures have been discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190210
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  • 10
    Electronic Resource
    Electronic Resource
    Mesomorphic solutions of cellulose triacetate in halogenated organic acids and mixtures of trifluoroacetic acid and dichloromethane (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1449-1460 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Cellulose triacetate (CTA) forms liquid-crystalline solutions in trifluoroacetic acid, dichloroacetic acid, and mixtures of trifluoroacetic acid and dichloromethane. Brilliant iridescent coloration, high optical rotations, and birefringent regions with swirl-like fingerprint patterns suggested the formation of cholesteric liquid crystals. Trifluoroacetic acid-dichloromethane is a particularly excellent solvent mixture to form liquid-crystal solutions of cellulose acetate. Crude bulk viscosity measurements confirm the formation of an anisotropic phase, and the temperature dependence of the critical concentration for formation of the anisotropic phase, obtained by bulk viscosity measurements at various temperatures, provides confirming evidence. Viscosity decreases with aging, suggesting that CTA is slowly degraded in the solvents studied. This is also confirmed by optical rotatory measurements and by polarizing microscope observations. The miscibility gap is observed as a function of molecular weight, and the differences between the experimental data and Flory's prediction are discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190916
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