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Poly-1,6-Diselenahexamethylene, 1,2-diselenane, and their effects on vinyl polymerizations (1967)

Brown, J. R. ; Gillman, G. P. ; George, M. H.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 903-916

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ISSN: 0449-296X

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Poly-1,6-diselenahexamethylene has been prepared, and some of its properties and those of its depolymerization product, 1,2-diselenane, have been studied. Depolymerization probably occurs by a free-radical mechanism. The effects of these organoselenium compounds on the thermal polymerization of styrene, methyl methacrylate, vinyl acetate, and acrylonitrile at 60°C. in the presence and absence of 2,2′-azobisisobutyronitrile and on the direct photopolymerization of these vinyl monomers at 25°C. has been examined. Various reaction mechanisms are suggested to explain the experimental results.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1967.150050416

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