ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Poly(arylene sulfones) prepared by friedel-crafts reactions (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 1802-1804 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: No Abstract
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.150050728
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Polymerization of styrene with VOCl3-aluminum alkylsNational Chemical Laboratory Communication No. 984. (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 2079-2089 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of styrene with VOCl3 in combination with AlEt3 and with Al(i-Bu)3 in n-hexane at 40°C. has been investigated. The rate of polymerization was found to be second order with respect to monomer in both systems. With respect to catalyst the rate of polymerization was first order for VOCl3-AlEt3 and second order for VOCl3-Al(i-Bu)3 systems. The activation energies for VOCl3-AlEt3 and VOCl3-Al(i-Bu)3 systems were 7.37 and 11.25 kcal./mole, respectively. The molecular weight of polystyrene in the AlEt3 system was considerably higher than that in the Al(i-Bu)3 system. The valence of vanadium obtained by a potentiometric method showed that the catalyst sites in the AlEt3 system are different in nature from those in the Al(i-Bu)3 system. The effect of diethylzinc as a chain-transfer agent in the AlEt3 system was also studied.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.150050824
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Arylene-modified siloxanes (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 2745-2755 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyarylenepolysiloxanes with varied structure can be obtained in condensation reactions of arylenedisilanols and N-methylsiloxazanes. Molecular weights, viscometric properties, glass transition temperatures, and thermogravimetric analysis data are reported.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.150051103
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Polymerization of styrene with the VOCL3-AlEt2Br catalyst system (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 665-673 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rate of polymerization with the VOCl3-AlEt2Br catalyst system at 30°C. in n-hexane reached a maximum at an Al/V molar ratio of 1.5. At this ratio, the rate of polymerization was first-order with respect to catalyst and second-order with respect to monomer concentrations. The apparent activation energy calculated was 6.4 kcal./mole. Diethylzine was found to act as a chain transfer agent. However, the molecular weights of polymers obtained were low. The possibility of bromide-containing catalyst sites acting in the termination reaction has been investigated. The average valence of vanadium is discussed in relation to molecular weights.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.150050323
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Nylon 1313: Synthesis and polymerization of monomers (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 391-394 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.150050214
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Annealing and melting of poly-4-methylpentene-1 single crystals (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 493-509 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The effects of thermal treatment at temperatures in the 177-250°C. range for 2 hr. on solution-grown single crystals of poly-4-methylpentene-1 have been studied by using electron microscopy. Crystals were grown both from 0.02% pentyl acetate solution at 110°C. and from 0.02% toluene solutions at temperatures less than 80°C. A number of distinct types of crystals have been obtained in the same or in separate solutions depending on the crystallization conditions. These crystals have some morphological characteristics in common such as a square outline with well-defined faces. The contrasting features include such things as a marked difference in relative size, with the smaller crystals showing extensive overgrowth and collapse markings. Observations by means of differential scanning calorimetry (DSC) on the melting behavior of these various crystals show the presence of distinct and characteristic melting points. The effects of a given thermal treatment depend on the type of crystals used, with the larger crystals showing greater stability. The first effects are the appearance of lines, notches at the edges, and holes. An increase in temperature results in an increase in these effects with the formation of fibrillar structures. Consideration is given to the influence of molecular conformation and molecular chain folding on the observed results.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.160050309
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Apparatus for the measurement of the flow birefringence of polymer melts (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 781-790 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A description is given of a modified cone-and-plate apparatus suitable for the measurement of the streaming birefringence of molten polymers. Some results are given of measurements on a polystyrene and a poly(dimethyl siloxane). Those on polystyrene are compared with solution measurements of the same material by use of the well-known Bueche-Harding parameter. Measurements on the silicone oil have been compared with measurements of the dynamic moduli on the same material, after ascertaining the validity of the stress-optical law for this system as well.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.160050413
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Molecular dimensions of polydipropylsiloxamer (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 829-838 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The molecular dimensions of polydipropylsiloxamer were studied by intrinsic viscosity measurements in toluene and in 2-pentanone. The relationships between the molecualr weight and the intrinsic viscosity were found to be: [η]25°C., toluene = 4.35 × 10-4 M0.58; [η]θ(10°C.), toluene = 1.09 × 10-3 M0.5; [η]θ(76°C.), 2-pentanone = 8.71 × 10-4 M0.5. This held reasonably well for molecular weights from 25,000 to 3000,000. The root-mean-square end-to-end length ratio, (r02/M)1/2 as calculated from the constant K, exceeds the free rotation value by approximately 100%. The disparity is greater than that found with polydimethylsiloxamer, indicating a lower degree of flexibility for the polydipropylsiloxamer. This is largely due to the short range steric interaction between near neighboring units of the chain. Gel permeation chromatography was also employed to demonstrate the lower degree of flexibility for polydipropylsiloxamer as compared with polydimethylsiloxamer.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.160050503
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Sorption of organic vapors into drawn and undrawn polyethylene (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 957-972 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Drawing of linear polyethylene at 60°C. to an extension ratio of ten drastically reduces the sorption and diffusion of n-pentane, benzene, methylene chloride, and tetrachloroethylene. Methylene chloride was chosen for more detailed study. The sorption is of the normal Fickean type. It is also fully reversible in the temperature range between 25 and 45°C. if the sorbed amount is kept to below 0.5%. At higher concentrations the sample relaxes so that sorption irreversibly increases. The reversible sorption per gram of amorphous component is about 1/6 of that in undrawn polyethylene. The diffusion constant has a larger temperature and concentration dependence than in the undrawn material. At zero concentration the activation energy for diffusion is 34.4 kcal./mole and the diffusion constant at 25°C. is 8 × 10-11 cm.2/sec. as compared with 14.4 kcal./mole and 1.5 × 10-8 cm.2/sec. in undrawn PE. Cold drawing reduces the sorption sites without changing their energy content, but drastically cuts down diffusion and increases the activation energy. A smaller part of the increase of the latter is a consequence of the lower enthalpy of the amorphous material and a larger part is probably due to the increased distance between sorption sites.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.160050512
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Recording microdilatometer for the measurement of polymer crystallization rates (1967)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 5 (1967), S. 391-393 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1967.160050213
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...