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  • Physics  (69)
  • Chemical Engineering  (66)
  • 1980-1984  (135)
  • 1982  (135)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 514-515 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 765-772 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized mathematical model is developed to describe the process of multicomponent adsorption on activated carbon in fixed beds. Numerical, finite difference, solutions for the adsorption of binary, and ternary organic mixtures are shown to satisfactorily match previously published experimental data.
    Additional Material: 9 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 199-207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A series of seven coals of different ranks and from various locations were heated in an inert atmosphere under relatively mild conditions to measure the rates of gas evaporation. Samples crushed to various fractions in the particle size range -6+50 U.S. mesh were studied at temperatures in the range of 150 to 300°C. The results show that: (1) most water is released at 100°C, evidently an evaporation process, (2) CO2 is evolved at 150°C and above, and (3) CO is evolved at 250°C and above. An interpretive model was developed to fit the CO2 production rate and kinetic constants were obtained. Gas evolution rates are independent of particle size for the most porous coals, but vary among coals, depending on both chemical composition and physical structure. A 15% loss in heating value was incurred during drying and subsequent oxidation when the pretreatment temperature was increased from 150 to 225°C.
    Additional Material: 12 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 575-582 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The hindered amine-induced decomposition of polypropylene hydroperoxide was studied in the solid state and in the presence of a liquid solvent and the polymer was compared with model hydroperoxides. The high reactivity of the macrohydroperoxides appears to be related to the adjacent, hydrogen-bonded hydroperoxide groups that occur in the polymer. The hindered amines are converted to nitroxides in the reaction via hydroxylamine intermediates. Amine-induced decomposition of polypropylene hydroperoxide is faster in the absence of a liquid solvent for the amine than in the presence of the solvent, probably because of the strong amine-hydroperoxide association that occurs in the solid state. The decomposition process in the solid state is sufficiently rapid for the reaction to contribute to the effectiveness of hindered amines in the light stabilization of polymers.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 1503-1509 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Small- and wide-angle x-ray scattering results for a series of un-neutralized and neutralized sulfonated polystyrenes are presented for the range of sulfonation from 0 to 7.26 mol %. From the small-angle scattering it is shown that above the 3 mol % level for both the zinc and sodium salts, a Bragg spacing (37 Å) and diameter (6.9-8.4 Å) of the scattering unit can be calculated. When the concentration of salt is increased, there is no appreciable change in the latter two measurements. The wide-angle data indicate that the cations do not influence to any large extent the basic intramolecular and intermolecular structure of polystyrene. All the data are consistent with the onset of clustering above a critical ion concentration.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 329-344 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method of optimizing the fiber drawing process involving the feed roll, the heated elements and the take-up roll is presented. In this method, the process is described in terms of the filament temperature and filament extension in the drawing zone. This is in contrast to the conventional approach in which the machine control variables such as the heated element temperature, fiber feed velocity and the total draw ratio were used to describe the process. It is shown that the drawing process seldom proceeds by a simple yielding mechanism and that a one-step drawing process usually involves a yield draw followed by a post-yield stretching. Using the drawing of nylon 6 fibers as an example, it is shown that the most critical factors related to achieving the highest fiber strength in drawing from a given precursor are the yarn temperature and yarn extension at yielding and during the post-yield drawing.
    Additional Material: 17 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 1019-1028 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Liquid-crystalline solutions of cellulose triacetate (CTA) in trifluoroacetic acid (TFA)-CH2Cl2, TFA-1.2-dichloroethane (1,2-DCE) solvent mixtures were examined by means of PMR spectroscopy. CTA forms both cholesteric and nematic phases in these solvents depending on the CTA concentration. In cholesteric solutions the CH2Cl2 signal is initially a singlet and then splits into a doublet. The time dependence of the splitting and the effect of CTA concentration are reported. The results suggest that the cholesteric phase slowly changes into a nematic phase in the magnetic field. The splitting of the CH2Cl2 proton signal into a doublet and the 1,2-DCE signal into a quartet are due to direct magnetic dipole-dipole interactions. Rotation of the sample in the magnetic field results in the disappearance of the doublet or quartet and suggests that the solvent molecules are originally oriented in the direction of the magnetic field. In the biphasic region, immediate splitting of the CH2Cl2 proton signal suggests that the anisotropic phase is nematic.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 509-521 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The protonation of a heterocyclic rigid-rod polymer poly(p-phenylene benzbisthiazole) and its model compound has been studied by UV-visible and Raman spectroscopy. Because of the two nitrogens on the heterocyclic ring, spectroscopic features of unprotonated, half-protonated, and fully protonated structures have been identified. For the fully protonated molecule, there is also an increase in conjugation between the phenyl ring and the heterocyclic ring.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 103-111 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A high-temperature molten carbonate electrochemical cell has been tested for use as a carbon dioxide concentrator in a manned spacecraft. Carbon dioxide is removed from a stream of cabin air supplied to the cathode of the bench scale cell. It is then concentrated through the molten carbonate electrolyte to the anode. The anode is fed either hydrogen (energy producer) or nitrogen (substance producer). Performance variation with gas flow rate, cell temperature, carbon dioxide partial pressure, and current are presented and analyzed.
    Additional Material: 16 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 392-396 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The results of batch settling tests with various coal powders in model oils indicated that the viscosity and the aromatic/paraffinic nature of the oil influences the sedimentation and the aggregation rate of the particles. Oxidation of paraffin oil may result in the generation of surface active agents which retards the sedimentation of certain coals.
    Additional Material: 1 Ill.
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