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  • 1
    Electronic Resource
    Electronic Resource
    The rate of the reaction of OH with HCl (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 1151-1160 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The absolute rate constant for the OH + HCl reaction has been measured from 240 to 295 K utilizing the techniques of laser/flash photolysis-resonance fluorescence. The HCl concentrations were monitored continuously by ultraviloet and infrared spectrophotometry. The results can be fit to the following Arrhenius expression: \documentclass{article}\pagestyle{empty}\begin{document}$$k_1 = (4.6{\rm } \pm {\rm }0.3){\rm } \times {\rm }10^{ - 12} \exp [- (500{\rm } \pm {\rm }60)/T{\rm cm}^3 /{\rm molecule} \cdot {\rm s}$$\end{document} The rate constant values obtained in this study are 20-30% larger than those recommended previously for modeling of stratospheric chemistry.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550160910
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  • 2
    Electronic Resource
    Electronic Resource
    Kinetics of the reaction of OH with pernitric and nitric acids (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 16 (1984), S. 41-55 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The absolute rate constants for the reactions of OH + HO2NO2 (1) and OH + HNO3 (2) have been measured with the technique of flash photolysis resonance fluorescence over the temperature ranges of 240-330 K at 760 torr He for reaction (1) and of 240-370 K at 50 and 760 torr He for reaction (2). Reactant concentrations were monitored continuously by ultraviolet and infrared spectrophotometry. The data can be fitted to the following Arrhenius expressions: \documentclass{article}\pagestyle{empty}\begin{document}$$ k_1 = \left( {5.9 \pm 0.4} \right) \times 10^{ - 13} \exp \left[ {{{\left( {650 \pm 30} \right)} \mathord{\left/ {\vphantom {{\left( {650 \pm 30} \right)} T}} \right. \kern-\nulldelimiterspace} T}} \right]{{{\rm cm}^{\rm 3} } \mathord{\left/ {\vphantom {{{\rm cm}^{\rm 3} } {{\rm molecule} \cdot {\rm s}}}} \right. \kern-\nulldelimiterspace} {{\rm molecule} \cdot {\rm s}}} $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm CH}_{\rm 3} {\rm SiD}_{\rm 3} \mathop {\longrightarrow} \limits^3 {\rm CH}_{\rm 2} \raise1pt\hbox{=\kern-3.45 pt=} {\rm SiD}_{\rm 2} \left( {0.14} \right) $$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$ k_2 = \left( {8.3 \pm 0.9} \right) \times 10^{ - 15} \exp \left[ {{{\left( {850 \pm 40} \right)} \mathord{\left/ {\vphantom {{\left( {850 \pm 40} \right)} T}} \right. \kern-\nulldelimiterspace} T}} \right]{{{\rm cm}^{\rm 3} } \mathord{\left/ {\vphantom {{{\rm cm}^{\rm 3} } {{\rm molecule} \cdot {\rm s}}}} \right. \kern-\nulldelimiterspace} {{\rm molecule} \cdot {\rm s}}} $$\end{document} These results are in very good agreement with recent studies of reaction (2), and also of reaction (1) at 295 K.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550160107
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  • 3
    Electronic Resource
    Electronic Resource
    Tables of rate constants extracted from chemical kinetics and photochemical data for use in stratospheric modeling. Evaluation number 7 (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1135-1151 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: These tables of evaluated rate constants for use in stratospheric modeling have been taken from the most recent report of the NASA Panel that has been periodically producing such reviews. They are reproduced here to make a broader community aware of their existence. This article should NOT be cited, nor should these rate constants be used without consulting the full report. All citations should be to that original report (JPL Publ. 85-37), which contains extensive documentation and discussion of the rationale of the evaluation. Copies may be obtained by requesting JPL Publ. 85-37 from Documentation Services, 111-116B, Jet Propulsion Laboratory, 4800 Oak Grove Drive, Pasadena, CA 91109.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550171010
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