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Pressure and pH dependence of the kinetics of decarboxylative dechlorination of N-chloro-l-alanine (1996)

Brown, Michael C. ; Lepree, Jason M. ; Connors, Kenneth A.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 28 (1996), S. 791-797

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The kinetics of decarboxylative dechlorination of N-chloroalanine were studied at 25° in aqueous HCl solutions covering the pH range 1.4 to 2.8. These data were compared with literature results, and were interpreted in terms of first-order reactions of the cationic, uncharged, and anionic forms of the reactant. Pressure effect studies on the reaction of the anionic species yielded a volume of activation estimate of + 50 ± 3 cm3 mol-1. This result is consistent with a concerted fragmentation process. © 1996 John Wiley & Sons, Inc.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.1

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