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  • 1
    ISSN: 1573-5036
    Keywords: Ca deficiency ; critical Ca level ; crop response ; liming ; Mn toxicity nutrient interaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime, in combination with 3 kg Cu ha−1 plus 3 kg Zn ha−1, on yield and nutrient uptake by peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0–10 mm) coralline lime material containing 31.1% Ca and 1.7% Mg was used as lime at 0, 555, 2222 and 5000 kg ha−1. In the Togitogiga soil, which had the lowest level of exchangeable Ca, peanut yield increased by 6 fold after liming with 555 kg ha−1, relative to the unamended control. This yield increase was associated with reduced Mn toxicity as well as reduced Ca deficiency. The alleviation of Mn toxicity was not likely due to decreased Mn solubility because the lime application (555 kg ha−1) increased soil pH by 〈0.1 unit. Rather it was the increased Ca availability which reduced the Mn toxicity through a Ca/Mn antagonism. The critical range of exchangeable Ca for peanut growth was found to be about 1.5–1.6 cmol 1/2Ca2+ kg−1. A Ca/Mn-ratio 〉80 was required for a desirable Ca/Mn balance in peanut tissue. On the other two locations (with exchangeable Ca levels of 1.5–1.6 cmol 1/2Ca2+ kg−1), liming increased peanut yields by 15–20%. Additions of Cu plus Zn also increased the yields, although the increases were small (7%) and not significant at the 95% probability level.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 36 (1993), S. 211-219 
    ISSN: 1573-0867
    Keywords: banding ; broadcasting ; Ca deficiency ; crop response ; liming ; Mn toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime on yield and nutrient uptake by sweet corn (Zea mays saccharata Sturt.) and peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0-10 mm) coralline material containing 31.1% Ca and 1.67% Mg was used as lime. There were two modes of application: band and broadcast, and three rates: 6, 12 and 18 ton ha−1. In the highest rainfall location, marketable yields were increased by 250% for peanut and 160% for sweet corn by liming at 6 ton ha−1, relative to the unamended control. Peanut yield increases were associated with reduced Mn toxicity and/or with Ca and Mg deficiency. Sweet corn was less susceptible to Mn toxicity, but more responsive to exchangeable Ca. The critical level of exchangeable Ca was found to be about 2.0 cmol(+)kg−1. Applying lime to a band of 0.25-m wide did not reduce yield relative to broadcast. Soil cultivation caused the lime to spread over a wider band, diluting the applied calcium with a larger soil volume, suggesting that less than 6 ton ha−1 broadcast coarse coralline lime could still be adequate for most Samoan soils.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 5 (1992), S. 295-298 
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: To study molecular features connected with chirality, a procedure for the quantitative estimation of the chirality level of compounds of different classes is needed. A procedure for estimating the molecular asymmetry level relative to mirror-reflection axes of symmetry, S1, S2, S4 and S6, has been developed. The geometrical mean of these parameters is the disymmetry function (DF). To calculate the DF, the molecule must be fixed in the coordinate system, transferred to the main axes of inertia.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The efficiency of the developed method of dissymmetry functions was studied using various model systems. The alteration of the dissymmetry function was analysed with systematic variations of the bond lengths, valence angles and masses of atoms in model tetrahedra. The behaviour of the dissymmetry function was studied for conformationally labile systems and chiral polyhedra. In general, it was found that in all cases the alteration of the dissymmetry function is in agreement with the speculative representations of the changes in degree of chirality.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The activation energy parameters for the reaction of PdX42- (X=Cl-, Br-) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each case simplifies to kobs=k[L] where L=tu or seu, and only ligand-dependent rate constants are observed at 25°C. The ligand-dependent rate constants for the first identifiable step in the PdCl42- + X system is (9.1±0.1) × 103 M-1 sec-1 and (4.5±0.1) × 104 M-1 sec-1 for X=tu and seu, respectively, while for the PdBr42- + X system it is (2.0±0.1) × 104 M-1 sec-1 and (9.0±0.1) × 104 M-1 sec-1 for X=tu and seu, respectively.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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