ISSN:
0009-2940
Keywords:
λ5-Phosphoranes
;
Photoelectron spectroscopy
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Gas-Phase Reactions, 85[1]. - Preparation and Photoelectron Spectrum of Ethyldithioxo-λ5-phosphorane H5C2-P(=S)2The first alkyldithioxo-λ5-phosphorane 1a is obtained by selective monomerization of its readily accessible dimer, 2,4-diethyl-1,3,2λ5,4λ5-dithiadiphosphetane-2,4-dithione [4 (R = C2H5)], at 970 K in the gas phase and characterized by its photoelectron spectrum, which is assigned by both Koopmans' correlation and radical-cation state comparison with the halogen derivatives FPS2 (1b) and CIPS2 (1c).
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250207
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