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  • 1
    Electronic Resource
    Electronic Resource
    Photochemical pKa-Modulation and Gated Photochromic Properties of a Novel Diarylethene Switch (1999)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 2359-2366 
    Details
    ISSN: 1434-193X
    Keywords: Photochromism ; Diarylethenes ; Molecular devices ; Proton switches ; Merocyanines ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The unsymmetrical dithienylethene photochrome 1a exhibits proton-gated photochromic properties as well as novel chemical reactivity. The dimethoxylated derivative 9a represents a light-triggered proton switch whose dissociation constant is increased by a factor of 16 upon photochemical cyclization to 9b. Such compounds are of potential interest for multiplexing photochemical systems.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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