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A Comparison of Chemical and Photochemically Induced Reduction of Some 2(4),5-Dihydro-1,2,4-triazines and Aromatic 1,2,4-Triazines (1999)

Nagy, József ; Horváth, Anikó ; Szöllösy, Áron ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 685-689

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ISSN: 1434-193X

Keywords: Single-electron transfer ; Ring contractions ; 1,4-Dihydro-1,2,4-triazine ; Photochemical reduction ; Chemical reduction ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: -Chemical reduction (Zn/AcOH) of the arene 1 and of 2(4),5-dihydro-1,2,4-triazine 7 has been reinvestigated, resulting in the amendment of literature data concerning this reaction. Chemical, electrochemical, and photochemically induced reductions and ring contractions of 1,2,4-triazine derivatives have been compared. The first example of a triaryl-1,4-dihydrotriazine has been prepared. Some further evidence is presented that supports the proposed mechanism of the photochemically induced reduction and ring contraction of 1,2,4-triazines.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

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