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  • Phosphorus-sulfur compounds  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Spectroscopic Investigation of Various Phosphorus-Sulfur BondsDedicated to Professor H. Bredereck on the occasion of his 65th birthday (1969)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 8 (1969), S. 328-332 
    Details
    ISSN: 0570-0833
    Keywords: Phosphorus-sulfur compounds ; Bond theory ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The results of spectroscopic investigations on phosphorus-sulfur compounds, and particularly the force constants, reveal several factors that decisively influence the bonding. The effects of hybridization, the other bonding partners and their electronegativities, the π-bonding components, and the ionic charge are discussed. It is shown that the P—S bond, unlike the P—O bond, never attains full double bond character, despite its great variability.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196903281
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