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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Electron Microscopy Technique 8 (1988), S. 317-323 
    ISSN: 0741-0581
    Keywords: Superconductivity ; Perovskites ; Oxides ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Natural Sciences in General
    Notes: Twins are ubiquitous in the perovskite superconductors. They form during cooling from high temperatures through the tetragonal-to-orthorhombic phase transformation. Their behavior has been studied by transmission electron microscopy using a liquid-nitrogen-cooled specimen holder. It is observed that extra twins sometimes form in coarse-twinned regions to give a “refined” twin structure; this is thought to be induced by thermal stresses from the electron beam. Prolonged electron irradiation (with little beam heating) results in transformation to tetragonal with a loss of the twin structure; this is probably due to disordering of the oxygen sublattice by knock-on displacement. The same transformations can be induced by deliberate electron beam heating. In both cases the twinned orthorhombic structure can be restored by re-ordering of the oxygen ions, in the first case by removing the beam and in the second case by allowing the specimen to cool.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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