ISSN:
1434-193X
Keywords:
Carbene complexes
;
1-Metallahexatrienes
;
Cyclopentadienes
;
Carbene complexes
;
Tungsten
;
Domino cyclization
;
Pentalenes
;
Spirocyclopentanes
;
Spiro compounds
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
-1,3-Dioxytetrahydropentalenes 9 have been generated by base-catalyzed addition of protic oxygen nucleophiles ROH 6a-g (RO = carboxy or phenyloxy) to the [2-(1-cyclopentenyl)ethynyl]carbene tungsten complex 3. Compounds 9 are highly reactive and afford (cyclobutenyl)carbene complexes 12a-g through spontaneous [2+2] cycloaddition to a second molecule of the (1-alkynyl)carbene complex 3. Thermolysis of compounds 12 was found to generate indeno[b]-spiro-tricyclo[5.3.0.0]decadienes 18 through π-cyclization of the 1-tungsta-1,3,5-hexatriene unit involving insertion of carbon monoxide into the W—C bond.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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