ISSN:
0009-2940
Keywords:
Imidazoles
;
Pentacarbonyl metal complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Imidazole Derivatives, XI. - (C8H14N2)M(CO)5 (M = Mo, W) - Terminal Coordination of an Olefin in Pentacarbonyl Metal ComplexesHerrn Professor Reinhard Schmutzler zum 60. Geburtstag gewidmet.The 2-methylenimidazoline complexes (C8H14N2)M(CO)5 (M = Mo, W; 6) are obtained from M(CO)6 and 1,3,4,5-tetramethyl-2-methyleneimidazoline (5). Spectroscopic data reveal the strong donor character of the ylidic ligand in 6. The end-on coordination mode of the olefin is demonstrated by an X-ray structure analysis of 6a.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270814
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