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  • Pentacarbonyl(tetra-tert.-butyl-cyclotetrastibane)-tungsten complexes  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 817-822 
    ISSN: 0044-2313
    Keywords: Pentacarbonyl(tetra-tert.-butyl-cyclotetrastibane)-tungsten complexes ; μ-Tetra-phenyldistibanebis(pentacarbonyltungsten) ; X-Ray structure analyses ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Syntheses and Crystal Structure Analyses of Pentacarbonyl Tungsten Complexes with Tetratert.butyl Cyclotetrastibane and Tetraphenyldistibane LigandsThe synthesis of (tBuSb)4[W(CO)5]2 (1) is performed by reaction of (tBuSb)4 with W(CO)5THF in a 1:2 molar ratio. The reaction in the 1:1 ratio gives (tBuSb)4W(CO)5 (2). The crystal structures of 1 and (Ph4Sb2)[W(CO)5]2 (3) are reported.
    Notes: Die Synthese von (tBuSb)4[W(CO)5]2 (1) erfolgt durch Umsetzung von (tBuSb)4 und W(CO)5THF im Molverhältnis 1:2. Bei der Reaktion im Verhältnis 1:1 wird auch (t-BuSb)4W(CO)5 (2) gebildet. Über die Kristallstrukturanalysen von 1 und (Ph4Sb2)[W(CO)5]2 (3) wird berichtet.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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