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Synthesis and X-ray Structures of New Mononuclear and Dinuclear Diimine Complexes of Late Transition Metals (1999)

Laine, Timo V. ; Klinga, Martti ; Leskelä, Markku

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 959-964

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ISSN: 1434-1948

Keywords: Nickel ; Palladium ; Cobalt ; N ligands ; Crystal structures ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Synthesis of new palladium(II) (1), nickel(II) (2a and 2b), and cobalt(II) (3) complexes bearing the unsymmetrical, bidentate nitrogen ligand 2,6-bis(1-methylethyl)-N-(2-pyridinylmethylene)phenylamine (L) is described. The solid-state structures of 1, 2a, and 2b have been determined by single-crystal X-ray diffraction. The PdII compound exists in the monomeric form whereas the nickel complexes were observed as centrosymmetric dimers with slightly distorted square-pyramidal coordination sphere around each nickel center.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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