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  • 1
    Publication Date: 2011-12-21
    Description: The ballistics behavior of nitramine propellants containing RDX in an inert binder was examined. It is shown that at 2000 to 5000 psi, depending on the particle size, a slope break or discontinuity in the log burning rate versus log pressure curve occurs. It is shown that at higher pressures the nitramine decomposition proceeds predominately by C-N bond rupture and gives CH2 and N20. At still higher pressures (after the slope break) the decomposition proceeds by N-N rupture. The decomposition of RDX was investigated from 170 to 800 C at atmospheric pressure. The major decomposition products were CH2, CO, CO2, N20, N2, and H20. The ratio of the products varied with the pyrolysis rate and temperature.
    Keywords: PROPELLANTS AND FUELS
    Type: NASA. Langley Res. Center The 17th JANNAF Combust. Meeting, Vol. 2,; p 479-491
    Format: text
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  • 2
    Publication Date: 2011-12-21
    Description: The laboratory set up for determination of melting and thermodynamic properties of RDX using a diamond anvil cell apparatus capable of pressures exceeding 10 kbar and 250 C is described. The slope of the melting temperature versus applied pressure curve for RDX, as determined in the diamond cell, was found to equal 4.09 + or - 0.6 C (kbar). The density of liquid RDX at its melting point was calculated from this slope to be approximately 1.63 gm/cu cm. Practical and theoretical considerations in using the diamond anvil cell to generate thermodynamic data on RDX are discussed.
    Keywords: PROPELLANTS AND FUELS
    Type: NASA. Langley Res. Center The 17th JANNAF Combust. Meeting, Vol. 2,; p 527-536
    Format: text
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