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  • PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR  (2)
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  • 1
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    Lifetime and quenching of CO /a super 3 pi/ produced by recombination of CO2 ions in a helium afterglow. (1972)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: Demonstration that rapid dissociative recombination of CO2(+) in a flowing, helium afterglow is an efficient source of CO in the a super 3 pi metastable state. Ions produced by mixing CO2 with He(2 super 3 S) recombine to produce a CO metastable afterglow with a number density as great as 10 to the 9th per sq cm. Monitoring of the (a super 3 pi-X super 1 sigma) Cameron transition in CO was used to study the lifetime and quenching of CO (a super 3 pi) by CO2, N2, NO, and He. Recombination of CO2(+) also produces CO in the d super 3 delta and a' super 3 sigma states.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Chemical Physics; 56; Jan. 1
    Format: text
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  • 2
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    Absolute measurements of light emission from CO2/+/ and CO in the interaction of He/2 super 3 S/ with CO2. (1972)
    In:  Other Sources
    Details
    Publication Date: 2019-06-27
    Description: A flowing afterglow has been used to produce metastable He(2 super 3 S). It is shown that when He(2 super 3 S) interacts with a diatomic or triatomic molecule, its electronic excitation energy can be transferred to electronic and vibrational excitation of the molecule. To examine this mechanism, the rates for the production of electronically excited molecules, observed spectroscopically between 190 and 750 nm in the reaction of He(2 super 3 S) with CO2, have been measured. Results are tabulated.
    Keywords: PHYSICS, ATOMIC, MOLECULAR, AND NUCLEAR
    Type: Journal of Quantitative Spectroscopy and Radiative Transfer; 12; Mar. 197
    Format: text
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    NASA TECHNICAL REPORTS
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