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  • 36.40.+d  (1)
  • PACS. 78.70.Dm X-ray absorption spectra – 71.28.+d Narrow-band systems; intermediate-valence solids – 79.60.-i Photoemission and photoelectron spectra  (1)
  • PACS: 75.50.Cc; 78.20.Ls; 79.60.Cn  (1)
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  • 1
    ISSN: 1434-6036
    Schlagwort(e): PACS. 78.70.Dm X-ray absorption spectra – 71.28.+d Narrow-band systems; intermediate-valence solids – 79.60.-i Photoemission and photoelectron spectra
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract: A strong anisotropic distribution of the holes in Ni 3 d and O 2 p orbitals is observed in the polarization dependent O 1 s and Ni 2 p 3/2 X-ray absorption spectroscopy of the linear-chain nickelate Y2-xCaxBaNiO5 (x = 0, 0.05, 0.1, 0.2), which demonstrates the one-dimensional nature of the electronic state in these compounds. The holes introduced by Ca-doping occupy both O 2 p and Ni 3 d orbitals along the NiO5 chains. By comparing the experimental Ni 2 p 3/2 absorption spectra of Y2-xCaxBaNiO5 to those from charge transfer multiplet calculations we can derive the orbital character of the additional holes to be of ∼60% O2 p and ∼40% Ni 3 d.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1432-0630
    Schlagwort(e): PACS: 75.50.Cc; 78.20.Ls; 79.60.Cn
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract.  4 f Photoemission (PE) spectra from magnetically ordered rare-earth materials using circularly polarized X-rays exhibit strong Magnetic Circular Dichroism (MCD), i.e., the intensities of the individual multiplet lines depend on the relative orientation of sample magnetization and photon spin. On the example of the well- resolved Tb 4 f PE multiplet, it is shown that in relevant cases 4 f PE lines are esse ntially only observed for one magnetization direction, either parallel or antiparallel to the photon spin. These large MCD effects in 4 f PE open new perspectives in the analysis of surface and thin-film magnetism and provide a sensor for the degree of circular polarization of soft X-rays over a wide photon-energy range. To demonstrate the potential of MCD in 4 f PE as a magnetometer, we studied Gd(0001) and Tb(0001), where the magnetization of the topmost atomic (0001) layer can be easily separated from the bulk magnetization via the surface core-level shift. In multicomponent magnetic thin films containing different rare-earth elements, 4 f PE allows to monitor magnetization in an element-specific way, e.g., in case of the hetero-magnetic interface 1ML Eu/Gd(0001).
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 1434-6036
    Schlagwort(e): 36.40.+d ; 74.75.+t ; 79.60.−i
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The electronic structure of K-doped C60 was investigated by photoemission (PE) and X-ray absorption near-edge structure (XANES) studies at the C-1s and K-2p thresholds. In addition, information on the local K-derived partial density of states in superconducting K3C60 was obtained by resonant PE at the K-2p 1/2 threshold. The experimental observations support a complete charge transfer from K to C60 and we clearly observe a finite density of states atE F . From resonant PE, occupied states with K-p, d character could be identified in the binding-energy region from 1.5 to 8 eV below, but not directly at the Fermi level. This partial-density-of-states structure agrees well with the results of our band-structure calculations based on the local-density approximation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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