ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Fe(III)-Complexes with Mixed Ligands Consisting of Oxalate and Phenolate LigandsThe formation of mixed-ligand complexes between iron(III) ion, potassium oxalate and potassium salts of salicylic acid, sulfosalicylic acid, catechol, sodium 3,5-sulfocatechol („tiron“) and tetrachlorocatechol, respectively, has been investigated. There were obtained solid products with the approximate composition K3[Fe(C2O4)3-xLx] · n H2O (L = phenolat; x = 1; 2). For the synthesis of the above compounds ligand exchange reactions as well as addition-technique of oxalic acid followed by potassium phenolat to Fe2O3 · aq has been used. Through spectroscopic examination of the obtained products was found, that Fe3+-ion is simultaneously coordinated by oxalat and phenolat. Probably the products consist of at least two components as Fe(III) was found in two different bond states.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19793210110
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