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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 29 (1988), S. 121-133 
    ISSN: 1573-4889
    Keywords: Oxidation ; iron-chromium-carbon ; decarburization ; scales morphology ; cation diffusion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of Fe-Cr-C alloys containing 13% Cr and carbon ranging from 0.15 to 1.63% was studied at 1100°C for 3 hr. It was found that the oxidation rate increased with increasing carbon content in the alloys. The measured time variation of CO2 evolution showed that, during the first period of oxidation (0–40 min), a compact surface layer of FeO formed, which prohibited the free transfer of CO2 into the streaming oxidation atmosphere. The measurable CO2 evolution started between 40 and 50 min, and the most rapid evolution occurred in the interval t=60–90 min of oxidation. This effect corresponds well to scale-layer damage and to the maximum O2 absorption. The measurements carried out by the combined thermobalance-Chromatograph equipment were supplemented by metallographic investigation of the oxide layers. The results enabled us to interpret the primary stage of the oxidation of Fe-Cr-C alloys and to discuss the relations between the cation diffusivities in the individual oxide sublayers, i.e., in wustite, magnetite, and hematite.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 29 (1988), S. 419-433 
    ISSN: 1573-4889
    Keywords: Oxidation ; decarburization ; carbon diffusivity ; effect of oxidation atmosphere ; Fe, Cr, C
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Isothermal oxidation treatments were carried out on Fe-Cr-C steels. The steels containing 0.08, 0.15, 0.17, 0.88, 1.51, and 12.77wt.% Cr and 0.10, 0.49, 1.19, 0.18, 1.05, and 1.63 wt.% C were oxidized in ambient air at temperatures of 900, 1000, and 1200°C. Steels containing 13.22, 12.90, 12.52, and 12.77wt.% Cr and 0.15, 0.30, 0.50, and 1.63 wt.% C were heated (1100°C/3hr) in a flowing atmosphere of O2-N2-He in a SETARAM thermobalance. Evidence of decarburization of the steels is given by metallographic observations, by direct measurements of carbon diffusivities from the decarburization profiles in the oxidized samples, and by the results of kinetics measurements.3 Carbon diffusion coefficients were measured by the standard sectioning method in the samples oxidized in air. A. generalized equation for carbon diffusivity in Fe-Cr-C alloys is developed in terms of NCr[wt.%], NC[wt.%], and T[K].
    Type of Medium: Electronic Resource
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