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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 321 (1979), S. 75-85 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fe(III)-Complexes with Mixed Ligands Consisting of Oxalate and Phenolate LigandsThe formation of mixed-ligand complexes between iron(III) ion, potassium oxalate and potassium salts of salicylic acid, sulfosalicylic acid, catechol, sodium 3,5-sulfocatechol („tiron“) and tetrachlorocatechol, respectively, has been investigated. There were obtained solid products with the approximate composition K3[Fe(C2O4)3-xLx] · n H2O (L = phenolat; x = 1; 2). For the synthesis of the above compounds ligand exchange reactions as well as addition-technique of oxalic acid followed by potassium phenolat to Fe2O3 · aq has been used. Through spectroscopic examination of the obtained products was found, that Fe3+-ion is simultaneously coordinated by oxalat and phenolat. Probably the products consist of at least two components as Fe(III) was found in two different bond states.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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