ISSN:
0941-1216
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Photocatalytic Oxygenation of Cyclic Alkenes with Manganese(III)Tetraarylporphyrin ComplexesThe catalytic oxygenation of cyclohexene, 1-methylcyclohexene, α-pinene, 1,5-dimethylcycloocta-1,5-diene, and cis,trans-cyclodeca-1,5-diene with (tetraarylporphyrinato)manganese(III) complexes in the presence of molecular oxygen and visible light is reported. The photocatalytic reaction results in the formation of epoxides and allylic oxygenation products due to allylic hydrogen abstraction.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19923340312
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