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The Revised Structure of the Norditerpenoid Alkaloid Peregrine (1994)

de la Fuente, Gabriel ; Ruíz-Mesía, Lastenia ; Rodriguez, Matías L.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 77 (1994), S. 1768-1772

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The structure of peregrine (1), a norditerpenoid alkaloid isolated from Delphinium peregrinum var. elongatum BOISS., was revised on the basis of the 1H-COSY, HMQC, HMBC, and ROESY NMR spectra and of the X-ray analysis of its parent alcohol 2. Some of the 13C-NMR resonances of 1 and the related alkaloids peregrine alcohol (2), 14-O-acetylperegrine (3), bicoloridine (4), bicoloridine alcohol (5), 6-O-acetylbicolorine (6), bicolorine (7), and 14-O-acetylbicolorine (8), were also reassigned.

Additional Material: 4 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19940770708

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