ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Pulse radiolysis of oxygen-saturated bromobenzene yields a transient absorption with λmax = 480 nm at pulse end, which is identified as due to the BrO2-radical. To confirm this assignment the same radical was produced by flash photolysis of a Br2/O2-gas mixture and by chemical synthesis at low temperature. The absorption spectra of these BrO2-samples present a maximum between 480 and 380 nm dependent on the solvent. The influence of complex-formation on this absorption band is discussed. The ESR.-spectrum of chemically synthesized BrO2 is given.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19720550115
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