ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Variable-temperature and -pressure 13C-NMR studies of the 1,3,5-trithiane-capped triruthenium clusters [Ru3(CO)9{μ3-(η3-1,3,5-trithiane)}] (1) and [Ru3(t-BuNC)(CO)8{μ3-(η3-1,3,5-trithiane)}] (2) revealed that CO site exchanges occur via an intramolecular merry-go-round process, involving a transition state mostly dissociative in character.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19930760817
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