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  • Organic Chemistry  (1)
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    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1975 (1975), S. 1499-1512 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 13C-NMR Spectra of Epimeric N-Alkylnoratropine DerivativesThe 13C-NMR spectra of several tertiary and quaternary N-alkylnoratropine derivatives (i.e. 5/6 or 15/17, table 1) as well as those of some model compounds are described. The stereochemical dependence of the ring- and N-alkyl carbon atom chemical shifts on the alkyl group configuration at the nitrogen center is characterized by means of substituent effects.
    Notes: Die 13C-NMR-Spektren einer Reihe tertiärer und quartärer N-Alkylnoratropiniumsalze (z. B. 5/6 oder 15/17; s. Tabelle 1) sowie einiger Bezugssubstanzen werden beschrieben. Die Abhängigkeit der chemischen Verschiebung der Ring- und N-Alkylkohlenstoffatome von der Stereochemie am Ammoniumstickstoff wird durch Substituenteneffekte charakterisiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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