ISSN:
0170-2041
Keywords:
Sialic acid, 5-azido-
;
Neuraminic acid, N-acyl derivatives
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
This communication describes the first synthesis of the α-methyl ketoside of an N-unprotected neuraminic acid in the form of its methyl ester (Neu5NH21Me-α-2Me) (5a). This compound is a valuable intermediate for the synthesis of unnatural N-substituted sialic acids. Syntheses of Neusmyristoyl1me-α-2Me (5b) and Neuscyclopropanoyl1me-α-2Me (5c) are presented.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.1990199001201
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