ISSN:
0044-2313
Keywords:
Na28In14Sn15 Zintl compound
;
preparation
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Crystal Structure of Na28In14Sn15Na28In14Sn15 was prepared from the elements. The crystal structure was determined by single crystal X-Ray and neutron diffraction methods (aro = 2299.3(3) pm, F43m, Z = 8). The structure elements can be explained in terms of the Zintl concept together with the valence rules of electron deficiency compounds as derivates of the arachno-Borane B3H9.
Notes:
Na28In14Sn15 wurde aus den Elementen dargestellt und strukturell über Röntgen- und Neutronenbeugungsmethoden an Einkristallen charakterisiert (aro = 2299,3(3) pm, F43m, Z = 8). Die Strukturelemente lassen sich über das Zintl-Konzept deuten bzw. als Abkömmlinge des arachno-Borans B3H9 nach den Valenzregeln der Elektronenmangelverbindungen interpretieren.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19916060108
Permalink
