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  • Gas chromatography  (1)
  • NONMETALLIC MATERIALS  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 184-185 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, fused silica ; Alkene halohydrins ; Positional isomers ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The use of a fused silica capillary column for the gas chromatographic analysis of alkene halohydrin positional isomers is described. This method is illustrated with the complete resolution of the positional isomers for propylene bromohydrin, propylene iodohydrin, and allyl bromide bromohydrin. Comparison with the resolution obtained on a packed column is also provided.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-06-28
    Description: Superplasticity has been demonstrated in many fine-grained structural ceramics and ceramic composites, including yttria-stabilized tetragonal zirconia polycrystal (YTZP), alumina, and Al2O3-reinforced zirconia (Al2O3/YTZ) duplex composites and SiC-reinforced Si3N4. These superplastic ceramics obviously offer the potential benefit of forming net shape or near net shape parts. This could be particularly useful for forming complicated shapes that are difficult to achieve using conventional forming techniques, or require elaborate, subsequent machining. In the present study, we successfully demonstrated the following: (1) superplastic 3Y-TXP and 20 percent Al2O3/YTZ composite have for the first time been successfully deformed into hemispherical caps via a biaxial gas-pressure forming technique; (2) no experimental difficulty was encountered in applying the required gas pressures and temperatures to achieve the results, thus, it is certain that higher rates of deformation than those presented in this study will be possible by using the current test apparatus at higher temperatures and pressures; and (3) an analytical model incorporating material parameters, such as variations during forming in the strain rate sensitivity exponent and grain growth-induced strain hardening, is needed to model accurately and therefore precisely control the biaxial gas-pressure forming of superplastic ceramics. Based on the results of this study, we propose to fabricate zirconia insulation tubes by superplastic extrusion of zirconia polycrystal. This would not only reduce the cost, but also improve the reliability of the tube products.
    Keywords: NONMETALLIC MATERIALS
    Type: NASA. Langley Research Center, Current Technology for Thermal Protection Systems; p 77-87
    Format: application/pdf
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