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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 3 (1974), S. 233-237 
    ISSN: 1572-8927
    Keywords: N-methylacetamide ; tetrabutylammonium bromide ; enthalpy of dilution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpy of dilution of tetra-n-butylammonium bromide in mixtures of water and N-methylacetamide has been measured from approximately 0.1 to 1.0m at 35°C. The mole fraction of water in the solvent varied from 0.250 to 0.969. The results are strikingly nonlinear in the mole fraction of water. As the mole fraction of water varies from 0 to 0.7, there is only a small change in the enthalpy of dilution. At higher mole fractions of water, the excess enthalpy rises sharply to the unusually high values found in water. This indicates that the unusually high values of excess enthalpy associated with hydrophobic bonding in water are destroyed by relatively small amounts of N-methylacetamide.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 3 (1974), S. 239-246 
    ISSN: 1572-8927
    Keywords: Heat of mixing ; N-methylacetamide ; electrolytes ; crosssquare rule
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The six possible heats of mixing of the system Na+, Pr4N+−Br−, I− have been measured at 35°C in the solvent N-methylacetamide at an ionic strength of 0.5. The cross-square rule of T. F. Young(1,2) does not hold accurately, and there are strong attractive forces between a cation and an anion. The largest effect in the heats of mixing is the formation of tetra-n-propylammonium iodide interactions. The data is compared to that of the Na+,K+−Cl−,NO 3 − system in water.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 3 (1974), S. 215-232 
    ISSN: 1572-8927
    Keywords: Enthalpy ; dilution ; N-methylacetamide ; alkali halides ; tetraalkylammonium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpies of dilution of some alkali and tetraalkylammonium halides have been measured in N-methylacetamide at 35°C. The results approach the Debye-Hückel limiting law at low concentrations. Excess free energies and entropies were calculated from the present results and previous freezing point measurements. The excess enthalpies of the alkali halides in N-methylacetamide are in the same range as the excess enthalpies in water. The effect of changing anions is quite small in N-methylacetamide. The cation order is Li+≃Na+〉Cs+〉K+. The excess enthalpies of the tetraalkylammonium halides in N-methylacetamide are very different from the excess enthalpies in water, confirming the conclusion that in water the large excess enthalpies are due to hydrophobic bonding and that in N-methylacetamide this effect is not present.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 24-32 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two time delay compensation techniques, the Smith predictor and the analytical predictor, are used for bottom composition control of a pilot scale methanol-water distillation column. The closed-loop performance of the two predictor schemes is compared to that for a proportional-integral controller in experimental and simulation studies. The predictors resulted in improved control for both set point and feed flow disturbances.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 456-460 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Continuous foam fractionation has a great deal of promise as a chemical engineering separation technique; however more information is needed concerning the effect of operating variables upon the separation which may be obtained. An experimental investigation is presented of the influence of temperature, of liquid residence time, and of the position of feed introduction upon the foam fractionation of the ethylhexadecyldimethylammonium bromide-water system. The study involves three series of experiments and ninety foam separation runs. For a given air rate and feed stream concentration and rate, the drain stream concentration and rate increase linearly with temperature and the foam concentration and enrichment ratio are increasing functions of temperature. Equations derived from a multiple linear regression analysis enable the calculation of the drain stream concentration and rate from the feed concentration, air rate, and temperature.Based upon experiments involving the variation in liquid residence time by two methods, changes in solution height have no influence upon the separation, indicating the rapid achievement of equilibrium. Changes in feed rate and air rate show that the volume of air employed per unit volume of feed treated is a prime variable affecting the separation.Positioning the feed inlet at the solution-foam interface, compared with feeding into the solution, provides a significant increase in drain rate and decrease in drain concentration. Moving the feeder higher into the column of foam results in a continued decrease in drain concentration, but in the passage of the drain rate and foam concentration through maximum values at a height corresponding to approximately the midpoint of the column of foam.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 2 (1962), S. 193-201 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The probable molecular structure resulting from a reaction of equal parts of a Bisphenol A/Epichlorohydrin epoxy and a Tolylene Diisocyanate Prepolymer with a selected diamine has been identified by using spectrometry. This identification presents additional opportunities for attaching other complex molecules to either of the basic resins. Not only can this technique lead to an interesting family of hybrid plastics, but it is another step toward designing specific molecules for specific applications.
    Additional Material: 17 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 43 (1971), S. 23-32 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Die Prozeßdynamik befaßt sich mit dem zeitabhängigen Verhalten von geregelten und ungeregelten Prozessen, wenn diese Störungen unterliegen. Mathematische Modelle des dynamischen Verhaltens verfahrenstechnischer Teilprozesse und komplexer Anlagen lassen sich analytisch oder experimentell gewinnen und auf Analog- oder Digitalrechnern abbilden. An einigen einführenden Beispielen werden verschiedene Wege der Modellerstellung erlätert sowie die Methodik aufgezeigt, welche dem Wissensgebiet Prozeßdynamik zugrunde liegt.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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