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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 149-156 
    ISSN: 0009-2940
    Keywords: Cyclobutene, ring-opening ; Poly Diels-Alder reaction ; Molecules, double-stranded ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyclobutene Ring Opening: A Useful Reaction for the Synthesis of Double-Stranded MoleculesSyntheses and ring-opening reactions of the compounds endo-5a - e and 9a - c, all containing cyclobutene rings, are described. From these experiments it is concluded that compound 9a is a useful AB-type Diels-Alder monomer for the synthesis of well-defined double-stranded molecules. The stereochemistry of the adducts endo-4b and endo-5d is determined by X-ray structure analysis.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 433-445 
    ISSN: 0009-2940
    Keywords: Poly Diels-Alder reactions ; Molecules, double-stranded ; Configuration of double-stranded molecules ; Ladder polymers, spherical shape ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Structure Elucidation of a Double-Stranded Polymer by Using Model StudiesSyntheses and complete structural characterization (including constitution, configuration, conformation) of the double-stranded compounds Ua-5b, Ss-5b, U-7b, S-7b, UUa-8, SUs-8, UUUaa-9, USUas-9, SUUsa-9, and SSuss-9 are described. These compounds contain up to three repeating units of the ladder polymer 3 and are therefore used as model compounds to elucidate interesting structural aspects of this polymer. A model for the spherical shape of 3 is presented. The molecular structures in the crystals of S-7b, SUs-8, Ua-5b have been determined.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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